99529-52-9

Basic information

• Product Name: (2'E,4'E,1''R,2''R,6''R)-4-chloro-2-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>orcinol
• Synonyms: (2'E,4'E,1''R,2''R,6''R)-4-chloro-2-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>orcinol
• CAS NO: 99529-52-9
• Molecular Weight: 420.977
• Mol File: 99529-52-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (2'E,4'E,1''R,2''R,6''R)-4-chloro-2-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>orcinol(CAS DataBase Reference)
• NIST Chemistry Reference: (2'E,4'E,1''R,2''R,6''R)-4-chloro-2-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>orcinol(99529-52-9)
• EPA Substance Registry System: (2'E,4'E,1''R,2''R,6''R)-4-chloro-2-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>orcinol(99529-52-9)

Safety Data

• Hazardous Substances Data: 99529-52-9(Hazardous Substances Data)

Upstream product

• 85912-78-3 (+/-)-(2'Z,4'E)-3-<5'-(3,3-ethylenedioxy-1,2,6-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>-2,4-dimethoxy-6-methyl-1,4-cyclohexadiene 
• 85785-75-7 (+/-)-(2Z,4E)-5-(3',3'-ethylenedioxy-1',2',6'-trimethylcyclohexyl)-3-methyl-2,4-pentadienyl bromide 
• 85785-74-6 (+/-)-(2EZ,4E)-5-(3',3'-ethylenedioxy-1',2',6'-trimethylcyclohexyl)-3-methyl-2,4-pentadien-1-ol 
• 85785-73-5 (+/-)-(2EZ,4E)-5-(3',3'-ethylenedioxy-1',2',6'-trimethylcyclohexyl)-3-methyl-2,4-pentadienyl acetate 
• 85785-72-4 (+/-)-(2EZ,4E)-5-(1',2',6'-trimethyl-3'-oxocyclohexyl)-3-methyl-2,4-pentadienyl acetate 
• 85785-71-3 (+/-)-(2EZ,4E)-5-(1',2',6'-trimethyl-3'-oxocyclohexyl)-3-methyl-2,4-pentadien-1-ol 
• 85785-76-8 (+/-)-(2'Z,4'E)-<5'-(3,3-ethylenedioxy-1,2,6-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>-1,5-dichloro-6-methyl-2,4-cyclohexanedione 
• 85912-78-3 (2'E,4'E,1''R,2''R,6''R)-3-<5'-(3'',3''-ethylenedioxy-1'',2'',6''-trimethylcyclohexyl)-3'-methyl-2',4'-pentadienyl>-2,4-dimethoxy-6-methyl-1,4-cyclohexadiene 
• 85785-73-5 (2EZ,4E,1'R,2'R,6'R)-(-)-5-(3',3'-ethylenedioxy-1',2',6'-trimethylcyclohexyl)-3-methyl-2,4-pentadienyl acetate 
• 85785-72-4 (2EZ,4E,1'R,2'R,6'R)-(-)-5-(1',2',6'-trimethyl-3'-oxocyclohexyl)-3-methyl-2,4-pentadienyl acetate 
• 85785-71-3 (2EZ,4E,1'R,2'R,6'R)-(-)-5-(1',2',6'-trimethyl-3'-oxocyclohexyl)-3-methyl-2,4-pentadien-1-ol 
• 99477-53-9 (6R,7R,8R)-7-((1E,3E)-5-Chloro-3-methyl-penta-1,3-dienyl)-6,7,8-trimethyl-1,4-dioxa-spiro[4.5]decane 
• 89162-97-0 (R)-(+)-3,4-dimethyl-2-cyclohexen-1-one 
• 75337-05-2 (+)-(R)-4-methyl-2-cyclohexene-1-one 

Downstream Products

• 26166-39-2 (+/-) ascochlorin 
• 26166-39-2 3-Chloro-4,6-dihydroxy-2-methyl-5-[(2Z,4E)-3-methyl-5-((1S,2S,6S)-1,2,6-trimethyl-3-oxo-cyclohexyl)-penta-2,4-dienyl]-benzaldehyde 
• 91854-87-4 3-Chloro-4,6-dihydroxy-2-methyl-5-[(2Z,4E)-3-methyl-5-((6R,7R,8R)-6,7,8-trimethyl-1,4-dioxa-spiro[4.5]dec-7-yl)-penta-2,4-dienyl]-benzaldehyde 
• 99529-53-0 3-Chloro-4,6-dihydroxy-2-methyl-5-[(2E,4E)-3-methyl-5-((6R,7R,8R)-6,7,8-trimethyl-1,4-dioxa-spiro[4.5]dec-7-yl)-penta-2,4-dienyl]-benzaldehyde 
• 91854-87-4 3-chloro-4,6-dihydroxy-2-methyl-5-decane)-2,4-pentadienyl>benzaldehyde 

Relevant articles and documents

Total synthesis of (-)-ascochlorin via a cyclobutenone-based benzannulation strategy.

The application of a convergent benzannulation strategy in an efficient synthesis of (-)-ascochlorin is described.

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Three antibiotics with a common structural feature as prenylated phenols were synthesized: (+/-)-ascochlorin (5-chloro-2,4-dihydroxy-6-methyl-3-benzaldehyde), (+/-)-ascofurano