99683-11-1

Basic information

• Product Name: (E)-methyl 2-benzoyl-2-phenylthiopent-3-enoate
• Synonyms: (E)-methyl 2-benzoyl-2-phenylthiopent-3-enoate
• CAS NO: 99683-11-1
• Molecular Weight: 326.416
• Mol File: 99683-11-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-methyl 2-benzoyl-2-phenylthiopent-3-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-methyl 2-benzoyl-2-phenylthiopent-3-enoate(99683-11-1)
• EPA Substance Registry System: (E)-methyl 2-benzoyl-2-phenylthiopent-3-enoate(99683-11-1)

Safety Data

• Hazardous Substances Data: 99683-11-1(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 86895-69-4 methyl 2-phenylsulphinylpentanoate 
• 86895-65-0 α-phenylthio methyl pentanoate 
• 19129-92-1 methyl 2-bromovalerate 
• 66716-61-8 methyl (Z)-2-phenylthiopent-2-enoate 
• 93-97-0 benzoic acid anhydride 

Downstream Products

• 109542-20-3 methyl 2-benzoyl-4-oxopent-2-enoate 
• 99683-15-5 methyl 2-benzoyl-4-phenylthiopent-2-enoate 
• 99683-19-9 methyl 2-benzoyl-4-phenylsulphinyloxypent-2-enoate 
• 99683-24-6 methyl 2-benzoyl-3-phenylthiopentanoate 
• 99683-23-5 methyl 2-benzoylpent-2-enoate 
• 99683-26-8 (E)-methyl 2-(1-hydroxybenzyl)pent-3-enoate 
• 99683-25-7 (E)-methyl 2-benzoylpent-3-enoate 

Relevant articles and documents

Reactions of α-or χ-Phenylthio Substituted Extended Enolate Anions Derived from Esters

The title anions are alkylated and acylated (α series only) exclusively at the α position.The α-phenylthio products give χ-phenylthio compounds by the PhS shift and the PhS group may be removed from the products in a number of ways.