86895-65-0

Basic information

• Product Name: α-phenylthio methyl pentanoate
• Synonyms: α-phenylthio methyl pentanoate
• CAS NO: 86895-65-0
• Molecular Weight: 224.324
• Mol File: 86895-65-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: α-phenylthio methyl pentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: α-phenylthio methyl pentanoate(86895-65-0)
• EPA Substance Registry System: α-phenylthio methyl pentanoate(86895-65-0)

Safety Data

• Hazardous Substances Data: 86895-65-0(Hazardous Substances Data)

Upstream product

• 19129-92-1 methyl 2-bromovalerate 
• 108-98-5 thiophenol 
• 83818-64-8 ((Z)-1-Chloro-pent-1-enylsulfanyl)-benzene 
• 109-52-4 valeric acid 
• 42768-45-6 2-bromopentanoyl chloride 

Downstream Products

• 86895-69-4 methyl 2-phenylsulphinylpentanoate 
• 66716-61-8 methyl (Z)-2-phenylthiopent-2-enoate 
• 66716-92-5 methyl (E)-2-phenylthiopent-2-enoate 
• 99683-25-7 (E)-methyl 2-benzoylpent-3-enoate 
• 99683-26-8 (E)-methyl 2-(1-hydroxybenzyl)pent-3-enoate 
• 99683-23-5 methyl 2-benzoylpent-2-enoate 
• 99683-10-0 (E)-methyl 2-acetyl-2-phenylthiopent-3-enoate 
• 99683-15-5 methyl 2-benzoyl-4-phenylthiopent-2-enoate 
• 99683-24-6 methyl 2-benzoyl-3-phenylthiopentanoate 
• 99683-11-1 (E)-methyl 2-benzoyl-2-phenylthiopent-3-enoate 
• 99683-19-9 methyl 2-benzoyl-4-phenylsulphinyloxypent-2-enoate 
• 86895-81-0 (E)-methyl 2-methyl-2-phenylthiopent-3-enoate 
• 99683-07-5 (E)-2-Phenylsulfanyl-pent-2-enoic acid methyl ester 

Relevant articles and documents

SOLVOLYSIS OF 1-CHLORO-1-ALKENYL PHENYL SULFIDES. SYNTHESIS OF α-BROMO PHENYL THIOCARBOXYLIC ESTERS, α-BROMO ALKYL CARBOXYLIC ESTERS AND α-PHENYLTHIO METHYL CARBOXYLIC ESTERS

1-Chloro-1-alkenyl phenyl sulfides treated with bromine followed by hydrolysis or methanolysis give α-bromo phenyl thiocarboxylic esters and α-phenylthio methyl carboxylic esters.Direct oxidative solvolysis with bromine and alcohol give α-bromo alkyl carboxylic esters.

ACYLATION OF EXTENDED ENOLATE IONS FROM α-PHENYLTHIO(PhS-)CROTONATE ESTERS

C-Acylation, like alkylation, occurs at the α-position of title compounds to give unsaturated keto-esters from which the PhS group may be removed.