99907-98-9

Basic information

• Product Name: O-(3-(trifluoromethyl)phenyl)hydroxylamine
• Synonyms: O-(3-(trifluoromethyl)phenyl)hydroxylamine
• CAS NO: 99907-98-9
• Molecular Weight: 177.126
• Mol File: 99907-98-9.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: O-(3-(trifluoromethyl)phenyl)hydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: O-(3-(trifluoromethyl)phenyl)hydroxylamine(99907-98-9)
• EPA Substance Registry System: O-(3-(trifluoromethyl)phenyl)hydroxylamine(99907-98-9)

Safety Data

• Hazardous Substances Data: 99907-98-9(Hazardous Substances Data)

Upstream product

• 1239023-73-4 C₂₆H₁₂F₂₀N₂O₄ 
• 1423-26-3 (meta-(trifluoromethyl)phenyl)boronic acid 
• 328081-53-4 N-(3-trifluoromethylphenoxy)phthalimide 
• 98-17-9 3-Trifluoromethylphenol 

Downstream Products

• 75735-31-8 E-O-phenylbenzaldoxime 

Relevant articles and documents

An Activity-Based Sensing Fluorogenic Probe for Monitoring Ethylene in Living Cells and Plants

Ethylene (ET) is an important gaseous plant hormone. It is highly desirable to develop fluorescent probes for monitoring ethylene in living cells. We report an efficient RhIII-catalysed coupling of N-phenoxyacetamides to ethylene in the presenc

Rhodium(III)-catalysed cascade [3 + 2] annulation of: N -aryloxyacetamides with 3-(hetero)arylpropiolic acids: Synthesis of benzofuran-2(3 H)-ones

Herein, a cascade [3 + 2] annulation of N-aryloxyacetamides with 3-(hetero)arylpropiolic acids affording benzofuran-2(3H)-ones via rhodium(iii)-catalyzed redox-neutral C-H functionalization/isomerization/lactonization using an internal oxidative directing group O-NHAc was achieved. This catalytic system provides a regio- and stereoselective approach to synthesize (Z)-3-(amino(aryl)methylene)benzofuran-2(3H)-ones with exclusive Z configuration selectivity, acceptable yields and good functional group tolerance. Preliminary investigations on ultraviolet-visible and fluorescence behaviors reveal that the annulation products may be applied as a promising fluorescent probe for sensing metal cations, especially for cerium (Ce3+).

Rh(iii)-catalyzed and alcohol-involved carbenoid C-H insertion into N-phenoxyacetamides using α-diazomalonates

Here we report a new and mild Rh(iii)-catalyzed and alcohol-involved carbenoid C-H insertion into N-phenoxyacetamides using α-diazomalonates. This reaction provided a straightforward way for installing both an α-quaternary carbon center and a free-OH moiety into the phenyl ring, thus giving access to useful 2-(2-hydroxyphenyl)-2-alkoxymalonates with good substrate/functional group tolerance. This journal is