Synthesis and light-emitting properties of C60-containing poly(1-phenyl-1-Butyne (cas 107-00-6))s
-
Add time:08/27/2019 Source:sciencedirect.com
While WCl6–Ph4Sn is a poor catalyst for the polymerization of 1-phenyl-1-butyne (PB) at room temperature, it effectively polymerizes PB in the presence of C60, giving high molecular weight polymers in high yields. The polymers are soluble in common solvents such as THF and chloroform, and spectroscopic analysis reveals that C60 has copolymerized with PB. Thus, C60 plays the dual roles of comonomer and cocatalyst in the acetylene polymerization. While it has often been reported that C60 quenches photoluminescence (PL) of conjugated copolymers, the C60-containing polyacetylene emits strong blue light, whose intensity is about two times higher than that of the PL of the parent PPB.
We also recommend Trading Suppliers and Manufacturers of 1-Butyne (cas 107-00-6). Pls Click Website Link as below: cas 107-00-6 suppliers
Prev:Kinetic studies on the hydrogenation of 1,3-butadiene, 1-Butyne (cas 107-00-6) and their mixtures
Next:Chemical insights into the larger sooting tendency of 2-methyl-2-BUTENE (cas 107-01-7) compared to n-pentane) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Kinetic studies on the hydrogenation of 1,3-butadiene, 1-Butyne (cas 107-00-6) and their mixtures08/26/2019
- Effect of 2-butyne-1, 4-diol on silver electrodeposition from 5, 5-dimethyl hydantoin solutions08/25/2019
- Kinetic study of the liquid-phase hydrogenation of 1-Butyne (cas 107-00-6) over a commercial palladium/alumina catalyst08/24/2019
- Evaluation of 4-[18F]fluoro-1-Butyne (cas 107-00-6) as a radiolabeled synthon for click chemistry with azido compounds08/23/2019
- Kinetic study of the liquid-phase selective hydrogenation of 1-Butyne (cas 107-00-6) in presence of 1-butene over a commercial palladium-based catalyst08/22/2019
- Reaction dynamics of the phenyl radical (C6H5) with 1-Butyne (cas 107-00-6) (HCCC2H5) and 2-butyne (CH3CCCH3)08/21/2019
- Development of a multi-layer microreactor: Application to the selective hydrogenation of 1-Butyne (cas 107-00-6)08/20/2019
- A crossed molecular beams investigation of the reactions of atomic silicon (Si(3P)) with C4H6 isomers (1,3-butadiene, 1,2-butadiene, and 1-Butyne (cas 107-00-6))08/19/2019
- Application of a catalytic membrane reactor to the selective hydrogenation of 1-Butyne (cas 107-00-6)08/18/2019