Construction of Solely Lewis acidic sites on Zr-MCM-41 and the catalytic activity for the Prins condensation of β-pinene and paraformaldehyde to NOPOL (cas 128-50-7)

Add time:09/26/2019    Source:infona.pl

This work has firstly constructed purely Lewis acidic sites on MCM-41 successfully, for which Zr-MCM-41 catalysts with different Zr contents are prepared through the hydrolysis of ZrOCl2 on MCM-41, followed by calcination. Thus-prepared materials possess typical hexagonal mesostructures, irregular morphologies, large surface areas, and large pore sizes, as revealed by XRD, SEM, TEM, N2 adsorption, and DRIFT FTIR. UV–vis, Raman and XPS spectra prove the formation of isolated species in high dispersion on the surface of MCM-41. NH3-TPD analysis shows that the acid intensity of the catalysts is proportional to the content of Zr, and the acidity of Zr-MCM-41 with the Zr content of <0.5% is very weak. Pyridine-IR spectra show that the surface acidity is mainly consisted of Lewis acidity, and solely Lewis acidic sites are constructed on Zr-MCM-41(550) with a low Zr content < 0.5 wt%. More Lewis acidic sites exposed on the surface of Zr-MCM-41 are considerably important for promoting the titled Prins condensation.

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