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Cas Database |
| Name |
1-Propanol,3,3',3''-phosphinidynetris- |
EINECS | N/A |
| CAS No. | 4706-17-6 | Density | 1.136 g/mL at 25 °C |
| PSA | 74.28000 | LogP | 0.61550 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C9H21O3P | Boiling Point | 196-198 °C(Press: 1 Torr) |
| Molecular Weight | 208.238 | Flash Point | >110℃ |
| Transport Information | UN 2924 | Appearance | N/A |
| Safety | 26-36/37/39 | Risk Codes | 10-34 |
| Molecular Structure |
|
Hazard Symbols | C |
| Synonyms |
1-Propanol,3,3',3''-phosphinidynetri- (6CI,8CI);Hishicolin P 500;Phosphine,tris(3-hydroxypropyl)-;Pirugon PP 40;Tris(3-hydroxypropyl)phosphine;Tris(hydroxypropyl)phosphine; |
Article Data | 4 |
1-Propanol,3,3',3''-phosphinidynetris- Synthetic route
A
- 4706-17-6
tris(3-hydroxypropyl)phosphine
B
- 51805-42-6
tris(3-hydroxypropyl)phosphane oxide
| Conditions | Yield |
|---|---|
| hydrolysis; Yield given; Yields of byproduct given; |
- 107-18-6
allyl alcohol
A
- 4706-18-7
(3-Hydroxypropyl)phosphan
B
- 4706-16-5
bis-(3-hydroxy-propyl)-phosphine
C
- 4706-17-6
tris(3-hydroxypropyl)phosphine
| Conditions | Yield |
|---|---|
| im UV-Licht; |
| Conditions | Yield |
|---|---|
| With phosphan Irradiation.UV-Bestrahlung; |
- 29269-17-8
trimethyl 3,3',3''-phosphanetriyltripropionate
- 4706-17-6
tris(3-hydroxypropyl)phosphine
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 4h; |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran | 91% |
| Conditions | Yield |
|---|---|
| In N,N-dimethyl-formamide at 100℃; for 16h; | 90% |
| Conditions | Yield |
|---|---|
| In acetone at 20℃; Inert atmosphere; | 86% |
| Conditions | Yield |
|---|---|
| In acetonitrile at 80℃; for 24h; Inert atmosphere; | 82% |
| In acetonitrile for 16h; Inert atmosphere; Heating; | 79% |
| Conditions | Yield |
|---|---|
| In acetone at 20℃; Inert atmosphere; | 81% |
- 4706-17-6
tris(3-hydroxypropyl)phosphine
- 217815-52-6
(C5(CH3)5)RuCl(CO)(P((CH2)3OH)3)
| Conditions | Yield |
|---|---|
| In not given Irradiation (UV/VIS); Ar-atmosphere; in THF or MeOH/H2O, not specified; stirring and irradiating equimolar amts. for 1 h in quartz autoclave, then refluxing; solvent removal (vac.), chromy. (SiO2, ether, then ethyl acetate/MeOH=4:1), solvent removal (vac.), washing (H2O), drying, recrystn. (hot MePh); elem. anal.; | 78% |
1-Propanol,3,3',3''-phosphinidynetris- Specification
The 1-Propanol, 3, 3', 3''-phosphinidynetris-, with the CAS registry number of 4706-17-6, is also known as Tris(3-hydroxypropyl)phosphine. It belongs to the product category of Tertiary Phosphines. This chemical's molecular formula is C9H21O3P and molecular weight is 208.24. In addition, it must be stored in airtight containers and placed in a dry, ventilated place at room temperature. Meanwhile, it should be avoided contact with light.
Uses of 1-Propanol, 3, 3', 3''-phosphinidynetris-: it is used to produce other chemicals. For example, it is used to produce [(3-{Bis-[3-(dimethylamino-dimethyl-silanyloxy)-propyl]-phosphanyl}-propoxy)-dimethyl-silanyl]-dimethyl-amine. This reaction solvent Tetrahydrofuran. The yield is about 91 %.
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When you are using this chemical, please be cautious about it as the following:
This chemical may cause burns on contact. In addition, it is flammable. During using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
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