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Cas Database |
| Name |
3,5-Dimethylpiperidine |
EINECS | 252-730-6 |
| CAS No. | 35794-11-7 | Density | 0.794 g/cm3 |
| PSA | 12.03000 | LogP | 1.58070 |
| Solubility | slightly soluble in Water | Melting Point |
N/A |
| Formula | C7H15N | Boiling Point | 141.2 °C at 760 mmHg |
| Molecular Weight | 113.203 | Flash Point | 32.8 °C |
| Transport Information | UN 1993 | Appearance | clear colorless to light yellow liquid |
| Safety | 16-26-37/39 | Risk Codes | 10-36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
3,5-Lupetidine(7CI);3,5-Dimethylpiperidine; |
Article Data | 17 |
3,5-Dimethylpiperidine Synthetic route
- 591-22-0
3,5-Lutidine
- 35794-11-7
3,5-dimethylpiperidine
Conditions
| Conditions | Yield |
|---|---|
| With palladium on activated charcoal; hydrogen; acetic acid at 20℃; under 760.051 Torr; for 24h; Time; | 100% |
| Stage #1: 3,5-Lutidine With hydrogen; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In octane at 120℃; under 15001.5 Torr; for 22h; Stage #2: With water Catalytic behavior; chemoselective reaction; | 76 %Chromat. |
| With 5% active carbon-supported ruthenium; hydrogen; acetic acid In water at 90℃; under 22502.3 Torr; for 8h; Reagent/catalyst; Time; Autoclave; | 99.5 %Chromat. |
| With palladium on activated charcoal; hydrogen In ethanol at 150℃; under 71257.1 Torr; for 5h; Temperature; Pressure; Solvent; |
- 25115-68-8
3,5-dimethyl-piperidine-2,6-dione
- 35794-11-7
3,5-dimethylpiperidine
Conditions
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride; diethyl ether |
- 4295-92-5, 7446-84-6, 35878-31-0, 50901-09-2, 82950-73-0, 118139-25-6
meso-2,4-dimethylglutaric anhydride
- 35794-11-7
3,5-dimethylpiperidine
Conditions
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: ammonia 2: lithium alanate; diethyl ether View Scheme |
Conditions
| Conditions | Yield |
|---|---|
| for 18h; Heating; | 99% |
- 35794-11-7
3,5-dimethylpiperidine
- 140-10-3
(E)-3-phenylacrylic acid
Conditions
| Conditions | Yield |
|---|---|
| With 3,4,5-trifluorophenylboronic acid In xylene for 29h; Heating; | 99% |
- 35794-11-7
3,5-dimethylpiperidine
- 1821-12-1
4-Phenylbutyric acid
Conditions
| Conditions | Yield |
|---|---|
| With 3,4,5-trifluorophenylboronic acid In toluene for 16h; Heating; other reagents; | 99% |
| With 3,5-di-C10F21-C6H3-B(OH)2; 4 A molecular sieve In toluene for 15h; Heating; | 95% |
| With boric acid In toluene for 15h; Dean-Stark; Reflux; Green chemistry; chemoselective reaction; | 95% |
| With triethoxyantimony In toluene Acylation; Heating; | 44% |
- 35794-11-7
3,5-dimethylpiperidine
- 611-71-2, 611-72-3, 17199-29-0, 90-64-2
MANDELIC ACID
- 1445918-79-5
1-(3,5-dimethylpiperidin-1-yl)-2-hydroxy-2-phenylethanone
Conditions
| Conditions | Yield |
|---|---|
| With butylboronic acid; water; benzoic acid In toluene for 14h; Reagent/catalyst; Solvent; Temperature; Reflux; | 99% |
| With [2-[(2,2,6,6-tetramethylpiperidin-1-yl)methyl]phenyl]boronic acid; benzoic acid In toluene for 16h; Reagent/catalyst; Time; Concentration; Solvent; Reflux; Molecular sieve; | 99% |
Conditions
| Conditions | Yield |
|---|---|
| With PdCl2(PMePh2)2; oxygen; Potassium benzoate; benzoic acid In toluene at 20 - 100℃; for 18h; Sealed tube; | 98% |
- 35794-11-7
3,5-dimethylpiperidine
- 70132-91-1
2-chloro-5-nitro-4'-chlorobenzophenone
Conditions
| Conditions | Yield |
|---|---|
| With calcium carbonate In ethanol | 97% |
- 35794-11-7
3,5-dimethylpiperidine
- 32997-30-1
2-(3,5-dimethyl-piperidin-1-ylsulfanyl)-benzothiazole
Conditions
| Conditions | Yield |
|---|---|
| 97% |
3,5-Dimethylpiperidine Chemical Properties
The molecular formula of 3,5-Dimethylpiperidine(35794-11-7) is C7H15N and its formula weight is 113.2.
The density of 3,5-Dimethylpiperidine(35794-11-7) is 0.853 g/mL at 25 °C(lit.) and it has a boiling point of 144 °C(lit.). The refractive index is about 1.4454(lit.). Its flash point is 91 °F.
The chemical synonyms of 3,5-Dimethylpiperidine(35794-11-7) are 3,5-dimethyl-piperidin;3,5-dimethylpiperidine,mixtureofcisandtrans;3,5-DIMETHYLPIPERIDINE;35LPT;3,5-LUPETIDINE;AKOS BBS-00003678;HEXAHYDRO-3,5-LUTIDINE;3,5-Lupeptidine
The molecular structure of 3,5-Dimethylpiperidine(35794-11-7):
3,5-Dimethylpiperidine Toxicity Data With Reference
RTECS#: CAS# 35794-11-7: None listed
LD50/LC50: RTECS: Not available.
Carcinogenicity: 3,5-Dimethylpiperidine, mixture of cis and trans - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: The toxicological properties have not been fully investigated.
LD50/LC50: RTECS: Not available.
Carcinogenicity: 3,5-Dimethylpiperidine, mixture of cis and trans - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: The toxicological properties have not been fully investigated.
3,5-Dimethylpiperidine Safety Profile
Hazard Codes Xi,F
Risk Statements 10-36/37/38
Safety Statements 16-26-36/37/39-37/39-36
RIDADR UN 1993 3/PG 3
WGK Germany 3
HazardClass 3
PackingGroup III
Risk Statements 10-36/37/38
Safety Statements 16-26-36/37/39-37/39-36
RIDADR UN 1993 3/PG 3
WGK Germany 3
HazardClass 3
PackingGroup III
3,5-Dimethylpiperidine Specification
Chemical Stability: Not available
Conditions to Avoid: Incompatible materials, ignition sources.
Incompatibilities with Other Materials: Strong oxidizing agents, acids, acid chlorides, carbon dioxide, acid anhydrides.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Conditions to Avoid: Incompatible materials, ignition sources.
Incompatibilities with Other Materials: Strong oxidizing agents, acids, acid chlorides, carbon dioxide, acid anhydrides.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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3,5-Dimethylpiperidine
