Journal of Physical Chemistry p. 3818 - 3820 (1988)
Update date:2022-08-05
Topics: Trifluoromethyl radicals (?CF?) and triplet methylene radicals (3CH?) can participate in hydrogen atom transfer reactions with alkylsilanes. For example Trifluoromethyl radicals may undergo addition reactions with alkylsilanes, leading to the formation of carbon-silicon bonds Competing Abstraction Reactions The reaction may result in the formation of silicon-carbon bonds as alkyl groups are transferred to the silicon atom Reactivity of Alkylsilanes
Bell, T. N.
Marciniak, B.
Sherwood, A. G.
The recombination of CF3 and CH2SiF3 radicals was used to prepare CF3CH2SiF3 by collisional stabilization of the initially formed hot molecule, CF3CH2SiF3*.One fate of this hot species, not so far observed, is its decomposition to give CF3CH2 and SiF3 radicals, a process which leads to additional products.In separate studies of the reactions of 3CH2 with CF3CH2SiF3, the formation of CH3SiF3 is observed, and this is suggested to be through a 5-coordinate radical exchange process.
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