ALLYL(CHLOROMETHYL)DIMETHYLSILANE

Base Information

• Chemical Name: ALLYL(CHLOROMETHYL)DIMETHYLSILANE
• CAS No.: 33558-75-7
• Molecular Formula: C6H13ClSi
• Molecular Weight: 148.708
• Hs Code.: 2931900090
• Mol file: 33558-75-7.mol

Synonyms:(chloromethyl)dimethylallylsilane;Allyl(chloroMethyl)diMethylsilane;Allylchloromethyldimethyl silane;silane,(chloromethyl)dimethyl-2-propenyl;3-Chloromethyldimethylsilyl-1-propene;(chloromethyl)allyldimethylsilane;dimethyl(chloromethyl)allylsilane;Dimethylallylchloromethylsilane;allyldimethylchloromethylsilane;

Chemical Property of ALLYL(CHLOROMETHYL)DIMETHYLSILANE

Chemical Property:

• Vapor Pressure: 7.3mmHg at 25°C
• Refractive Index: n20/D 1.449(lit.)
• Boiling Point: 63-66oC50 mm Hg(lit.)
• Flash Point: 82 °F
• PSA: 0.00000
• Density: 0.907 g/mL at 25oC(lit.)
• LogP: 3.07710

Purity/Quality:

98%,99%, ^*data from raw suppliers

Allyl(chloromethyl)dimethylsilane >95.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10
• Safety Statements: 16

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Allyl(chloromethyl)dimethylsilane is a useful intermediate for the preparation of α-silyl alcohols, ethers, and amines.

Technology Process of ALLYL(CHLOROMETHYL)DIMETHYLSILANE

There total 5 articles about ALLYL(CHLOROMETHYL)DIMETHYLSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.6%

Chloro(chloromethyl)dimethylsilane (1719-57-9) + allylmagnesium bromide (2622-05-1) → allyl(chloromethyl)dimethylsilane (33558-75-7)

Guidance literature:

With 3-chloroprop-1-ene; In diethyl ether; for 3h; Heating;

Reference yield:

Chloro(chloromethyl)dimethylsilane (1719-57-9) + allyl bromide (106-95-6) + allylmagnesium bromide (1730-25-2) → allyl(chloromethyl)dimethylsilane (33558-75-7)

Guidance literature:

With magnesium;

Reference yield:

Chloro(chloromethyl)dimethylsilane (1719-57-9) + allyl bromide (106-95-6) → allyl(chloromethyl)dimethylsilane (33558-75-7)

Guidance literature:

Multistep reaction; (i) Mg, Et₂O, (ii) /BRN= 1731933/;

upstream raw materials:

Chloro(chloromethyl)dimethylsilane

allylmagnesium bromide

allyl bromide

allylmagnesium bromide

Downstream raw materials:

2,2-dimethyl-1-<1-<(S)-2-(methoxymethyl)pyrrolidinyl>>-2-sila-4-pentene

chloromethyldimethylphenylsilane

(but-3-en-1-yl)dimethyl(phenyl)silane

3,3-dimethyl-1-thia-3-silacyclopentane

Refernces

• 1、 Connolly,J.W.,Fryer,P.F.. "-". . p. 315 - 327. Retrieved 1971.
• 2、 -. "N-derivatives of 1-deoxy nojirimycin". . . Retrieved 2008/06/13.
• 3、 Zhun', V.I.,Tsvetkov, A. L.,Sheludyakov, V. D.,Lavygin, I. A.,Leitan, O. V.,et al.. "SYNTHESIS, MASS SPECTRA, AND PHYSICAL PROPERTIES OF ALLYLSILANES". . p. 1425 - 1431. Retrieved 2007/10/02.