1,2-Bis(2-furanyl)ethane-1,2-diol

Base Information

• Chemical Name: 1,2-Bis(2-furanyl)ethane-1,2-diol
• CAS No.: 4464-77-1
• Molecular Formula: C₁₀H₁₀O₄
• Molecular Weight: 194.187
• Mol file: 4464-77-1.mol

Synonyms:1,2-difurfuryl-1,2-ethanediol;1,2-di(2-furyl)-1,2-ethanediol;1,2-difurylethane-1,2-diol;1,2-di(furan-2-yl)ethane-1,2-diol;meso-1,2-di(2'-furyl)ethane-1,2-diol;1,2-bis(furan-2-yl)-1,2-ethanediol;

Chemical Property of 1,2-Bis(2-furanyl)ethane-1,2-diol

Chemical Property:

• PSA: 66.74000
• LogP: 1.63960

Purity/Quality:

99% ^*data from raw suppliers

1,2-Ethanediol,1,2-di-2-furyl- ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-Bis(2-furanyl)ethane-1,2-diol

There total 11 articles about 1,2-Bis(2-furanyl)ethane-1,2-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

furfural (98-01-1) → (2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + 1,2-di-furan-2-yl-ethane-1,2-diol (4464-77-1,69314-24-5,69314-25-6,116204-42-3)

Guidance literature:

With potassium hydroxide; at 20 ℃; under 760.051 Torr; Reagent/catalyst; Electrochemical reaction; Green chemistry;

DOI:10.1039/d0gc01720e

Reference yield: 11.0%

furfural (98-01-1) + allyl bromide (106-95-6) → 1-(furan-2-yl)but-3-en-1-ol (119619-39-5,119678-68-1,6398-51-2,144730-99-4) + meso-1,2-di(2'-furyl)ethane-1,2-diol (4464-77-1,69314-24-5,116204-42-3,69314-25-6) + 1,2-bis(furan-2-yl)-1,2-ethanediol (4464-77-1,69314-24-5,69314-25-6,116204-42-3)

Guidance literature:

allyl bromide; With samarium; iodine; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

furfural; With water; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.tetlet.2017.01.091

Reference yield: 11.0%

furfural (98-01-1) + allyl bromide (106-95-6) → 1-(furan-2-yl)but-3-en-1-ol (119619-39-5,119678-68-1,6398-51-2,144730-99-4) + meso-1,2-di(2'-furyl)ethane-1,2-diol (4464-77-1,69314-24-5,116204-42-3,69314-25-6) + 1,2-bis(furan-2-yl)-1,2-ethanediol (4464-77-1,69314-24-5,69314-25-6,116204-42-3)

Guidance literature:

allyl bromide; With samarium; iodine; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

furfural; With water; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.tetlet.2017.01.091

upstream raw materials:

furfural

water

allyl bromide

Downstream raw materials:

n-decyl acetate

1,10-decanediol diacetate

furil

Oxalic acid 2-ethoxyoxalyloxy-1,2-di-furan-2-yl-ethyl ester ethyl ester

Refernces

• 1、 Cao, Yiran,Knijff, Jasper,Delparish, Amin,d'Angelo, Maria Fernanda Neira,Noёl, Timothy. "A Divergent Paired Electrochemical Process for the Conversion of Furfural Using a Divided-Cell Flow Microreactor". . p. 590 - 594. Retrieved 2020/12/25.
• 2、 Cheng, Jun,Duan, Pengbo,Feng, Jun,Li, Jieqiong,Wang, Ye,Wu, Xuejiao,Xie, Shunji,Zhang, Haikun,Zhang, Qinghong. "Selectivity Control in Photocatalytic Valorization of Biomass-Derived Platform Compounds by Surface Engineering of Titanium Oxide". supporting information. p. 3038 - 3053. Retrieved 2020/11/03.