Diazene, (4-bromophenyl)(triphenylmethyl)-

Base Information

• Chemical Name: Diazene, (4-bromophenyl)(triphenylmethyl)-
• CAS No.: 53034-21-2
• Molecular Formula: C25H19BrN2
• Molecular Weight: 427.343
• DSSTox Substance ID: DTXSID70453241
• Nikkaji Number: J701.670K
• Mol file: 53034-21-2.mol

Synonyms:Diazene, (4-bromophenyl)(triphenylmethyl)-;53034-21-2;4-bromophenylazotriphenylmethane;SCHEMBL11298591;DTXSID70453241;[(4-Bromophenyl)azo]triphenylmethane

Chemical Property of Diazene, (4-bromophenyl)(triphenylmethyl)-

Chemical Property:

• XLogP3: 7.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 426.07316
• Heavy Atom Count: 28
• Complexity: 433

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(C2=CC=CC=C2)(C3=CC=CC=C3)N=NC4=CC=C(C=C4)Br

Technology Process of Diazene, (4-bromophenyl)(triphenylmethyl)-

There total 1 articles about Diazene, (4-bromophenyl)(triphenylmethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trityl chloride (76-83-5) + (4-bromophenyl)hydrazine (589-21-9) → 4-bromophenylazotriphenylmethane (53034-21-2)

Guidance literature:

With diethyl ether; anschliessendes Behandeln mit wss. H₂O₂ und wss. NaHCO₃;

DOI:10.1021/ja01118a012

Reference yield: 78.0%

α-(4-bromophenylazo)triphenylmethane (53034-21-2) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 4-bromo-1,1'-biphenyl (92-66-0)

Guidance literature:

With ammonium cerium(IV) nitrate; In acetonitrile; benzene; for 18h; Ambient temperature;

DOI:10.1246/bcsj.68.1707

Reference yield: 61.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + α-(4-bromophenylazo)triphenylmethane (53034-21-2) → 2-(4-bromophenyl)-1-phenylethyl nitrate

Guidance literature:

With ammonium cerium(IV) nitrate; In dichloromethane; acetonitrile; for 26h; Ambient temperature;

DOI:10.1246/bcsj.68.1707

upstream raw materials:

trityl chloride

(4-bromophenyl)hydrazine

Downstream raw materials:

C₁₇H₁₉BrNO

C₁₉H₁₀⁽²⁾H₅BrNO

4’-bromo-2-methoxy-1,1'-biphenyl

4'-bromo-3-methoxy-1,1'-biphenyl