1,2-Dithiocane

Base Information

• Chemical Name: 1,2-Dithiocane
• CAS No.: 6008-69-1
• Molecular Formula: C6H12S2
• Molecular Weight: 148.293
• Mol file: 6008-69-1.mol

Synonyms:

Chemical Property of 1,2-Dithiocane

Chemical Property:

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Use Description: 1,2-Dithiocane, a chemical compound, has applications across various fields. In the field of organic chemistry, it serves as a valuable starting material or reagent for the synthesis of complex organic molecules, potentially contributing to the development of pharmaceuticals, agrochemicals, and specialty chemicals due to its versatile structure. In the realm of materials science and polymer chemistry, this compound can be employed as a building block for the creation of specialized materials, such as polymers or coatings, with unique properties for applications ranging from electronics to catalysis. Additionally, in the field of coordination chemistry, 1,2-Dithiocane may find use as a ligand or chelating agent, forming stable complexes with metal ions, which have applications in catalysis, material synthesis, and analytical chemistry. Its adaptability as an intermediate, materials precursor, and chelating agent underscores its significance in advancing pharmaceuticals, materials science, and coordination chemistry in various fields.

Technology Process of 1,2-Dithiocane

There total 10 articles about 1,2-Dithiocane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.5%

1,6-dimercaptohexane (1191-43-1) → 1,2-dithiacyclooctane (6008-69-1)

Guidance literature:

With dihydrogen peroxide; at 25 - 30 ℃; for 1.5h; Temperature;

Reference yield: 72.0%

1-bromo-6-iodohexane (155345-54-3) → 1,2-dithiacyclooctane (6008-69-1)

Guidance literature:

With benzyltriethylammonium tetrathiomolybdate; In chloroform; at 28 ℃; for 3h;

Reference yield: 65.0%

1,6-dimercaptohexane (1191-43-1) → 1,2-dithiacyclooctane (6008-69-1) + 1,2,9,10-tetrathiacyclohexadecane (13375-94-5)

Guidance literature:

With iodine; triethylamine; In chloroform; at 20 ℃; for 5h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.inorgchem.7b01398

upstream raw materials:

1,6-dimercaptohexane

1 ,6-dibromohexane

1,2-dimethyl-3,8-dioxo-1,2,5,6-diazadithiocane

1,6-bis-acetylsulfanyl-hexane

Downstream raw materials:

1,6-bis(chlorosulfanyl)hexane

2,9-dithiadecane

1,6-bis-butylsulfanyl-hexane

1,6-dimercaptohexane

Refernces

• 1、 -. "Preparation method of rubber aid 1,6-bis(N,N-dibenzyl carbamyl disulfide) hexane". Paragraph 0022; 0025; 0028; 0031; 0034. . Retrieved 2020/06/09.
• 2、 Smith, Keith,Al-Zuhairi, Ali J.,El-Hiti, Gamal A.,Alshammari, Mohammed B.. "Comparison of cyclic and polymeric disulfides as catalysts for the regioselective chlorination of phenols". . p. 74 - 85. Retrieved 2015/10/20.