BIS(TRIFLUOROMETHYL)CHLOROPHOSPHINE

Base Information

• Chemical Name: BIS(TRIFLUOROMETHYL)CHLOROPHOSPHINE
• CAS No.: 650-52-2
• Molecular Formula: C2Cl F6 P
• Molecular Weight: 204.439
• Hs Code.: 2903799090
• Mol file: 650-52-2.mol

Synonyms:Phosphinouschloride, bis(trifluoromethyl)- (6CI,7CI,8CI,9CI);Bis(trifluoromethyl)phosphinous chloride; Chlorobis(trifluoromethyl)phosphine

Chemical Property of BIS(TRIFLUOROMETHYL)CHLOROPHOSPHINE

Chemical Property:

• Vapor Pressure: 876mmHg at 25°C
• Boiling Point: 21°C at 760 mmHg
• PSA: 13.59000
• LogP: 3.66170

Purity/Quality:

98%min ^*data from raw suppliers

BIS(TRIFLUOROMETHYL)CHLOROPHOSPHINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C,F
• Hazard Codes: C,F
• Statements: 17-34
• Safety Statements: 17-26-36/37/39-43

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS(TRIFLUOROMETHYL)CHLOROPHOSPHINE

There total 7 articles about BIS(TRIFLUOROMETHYL)CHLOROPHOSPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Bis(trifluormethyl)-monothiophosphinigsaeure (1486-19-7) → hydrogenchloride (7647-01-0,15364-23-5) + bis(trifluoromethyl)chlorophosphine (650-52-2) + mercury sulfide

Guidance literature:

With HgCl₂;

Reference yield: 38.0%

bis(trimethylsilyl)mercury (4656-04-6) + bis(trifluoromethyl)phosphinic chloride (646-71-9) → chloro-trimethyl-silane (75-77-4) + trimethylsilan (993-07-7) + bis(trifluoromethyl)chlorophosphine (650-52-2) + Bistrifluormethyltrimethylsiloxyphosphinoxid (32114-80-0)

Guidance literature:

warming up from -84°C to 20°C;

DOI:10.1021/ic50124a032

Reference yield: 25.0%

(difluorothiophosphoryl)thio-bis(trifluoromethyl)phosphine (52226-01-4) → thiophosphoryl chloride difluoroide (2524-02-9) + (S2PF2)2 (15538-60-0) + bis(trifluoromethyl)chlorophosphine (650-52-2) + bis(trifluoromethyl)trichlorophosphorane (353-77-5)

Guidance literature:

With chlorine; at room temp.;

upstream raw materials:

bis(trimethylsilyl)mercury

Bis(trifluormethyl)-thiophosphinsaeurechlorid

bis(trifluoromethyl)phosphinic chloride

Bis(trifluormethyl)-monothiophosphinigsaeure

Downstream raw materials:

n-Butylbis-trifluormethyl-phosphin

phenylbis(trifluoromethyl)phosphine

Bis(trifluormethyl)-heptafluor-n-propylphosphan

trifluoromethan

Refernces

• 1、 Cavell,Leary,Sanger,Tomlinson. "Trimethylsilyl esters of phosphorus acids. III. Esters of difluoro- and bis(trifluoromethyl)phosphinous and -thiophosphinous acids". . p. 1374 - 1380. Retrieved 2008/10/08.