Anthracene, 1,2,3,4,4a,9,9a,10-octahydro-

Base Information

• Chemical Name: Anthracene, 1,2,3,4,4a,9,9a,10-octahydro-
• CAS No.: 7389-11-9
• Molecular Formula: C₁₄H₁₈
• Molecular Weight: 186.297
• Mol file: 7389-11-9.mol

Synonyms:

Chemical Property of Anthracene, 1,2,3,4,4a,9,9a,10-octahydro-

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Anthracene, 1,2,3,4,4a,9,9a,10-octahydro-

There total 13 articles about Anthracene, 1,2,3,4,4a,9,9a,10-octahydro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

anthracene (120-12-7) → 9,10-dihydroanthracene (613-31-0) + 1,2,3,4,5,6,7,8,9,10-hexahydroanthracene (3485-60-7) + 1,2,3,4,9,10,11,12-octahydroanthracene (7389-11-9,85281-16-9) + 1,2,3,4-tetrahydroanthracene (2141-42-6) + 1,2,3,4,5,6,7,8-octahydroanthracene (1079-71-6)

Guidance literature:

With hydrogen; lithium aluminium tetrahydride; titanium tetrachloride; In n-heptane; at 200 ℃; for 3h; under 67505.4 Torr; Product distribution; other conditions: other solvents (diglyme, nonane, hexane), other times, other catalysts, other reagents (D₂O, H₂O/LiAlD₄), other temperatures;;

Reference yield: 12.0%

anthracene (120-12-7) → 9,10-dihydroanthracene (613-31-0) + 1,2,3,4,9,10,11,12-octahydroanthracene (7389-11-9,85281-16-9) + 1,2,3,4-tetrahydroanthracene (2141-42-6) + 1,2,3,4,5,6,7,8-octahydroanthracene (1079-71-6)

Guidance literature:

With hydrogen; nickel; In water; ethylene glycol; at 80 ℃; Product distribution; 0.1M NaCl, 0.1M H₃BO₃, pH 2.6-2.7 to 6.0-6.4;

Reference yield:

9,10-phenanthrenequinone (84-65-1) → 9,10-dihydroanthracene (613-31-0) + anthracene (120-12-7) + 1,2,3,4,9,10,11,12-octahydroanthracene (7389-11-9,85281-16-9) + 1,2,3,4-tetrahydroanthracene (2141-42-6)

Guidance literature:

With hydrogen; aluminum oxide; K₅PV₂Mo₁₀O₄₀; at 300 ℃; for 3.5h; under 25840 Torr; Title compound not separated from byproducts;

DOI:10.1002/(SICI)1521-3773(19991115)38:22<3331::AID-ANIE3331>3.0.CO;2-Z

upstream raw materials:

anthracene

9,10-phenanthrenequinone

dibenzobarallene

Refernces

• 1、 Kalenchuk,Koklin,Bogdan,Kustov. "Hydrogenation of naphthalene and anthracene on Pt/C catalysts". . p. 1406 - 1411. Retrieved 2018/10/31.
• 2、 Liu, Chengyun,Rong, Zeming,Sun, Zhuohua,Wang, Yong,Du, Wenqiang,Wang, Yue,Lu, Lianhai. "Quenched skeletal Ni as the effective catalyst for selective partial hydrogenation of polycyclic aromatic hydrocarbons". . p. 23984 - 23988. Retrieved 2013/11/19.