2,4-Dinitrophenylhydrazone nonanal

Base Information

• Chemical Name: 2,4-Dinitrophenylhydrazone nonanal
• CAS No.: 2348-19-8
• Molecular Formula: C₁₅H₂₂N₄O₄
• Molecular Weight: 322.364
• European Community (EC) Number: 634-993-2
• NSC Number: 408567
• Mol file: 2348-19-8.mol

Synonyms:2348-19-8;2,4-dinitrophenylhydrazone nonanal;Nonanal 2,4-dinitrophenylhydrazone;2,4-dinitro-N-[(E)-nonylideneamino]aniline;Nonanal, 2-(2,4-dinitrophenyl)hydrazone;NSC408567;NSC-408567;J-015125

Chemical Property of 2,4-Dinitrophenylhydrazone nonanal

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 99-103 °C
• Boiling Point: 458.3°Cat760mmHg
• PKA: 12.32±0.10(Predicted)
• Flash Point: 231°C
• PSA: 116.03000
• Density: 1.21g/cm³
• LogP: 5.77070
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 9
• Exact Mass: 322.16410520
• Heavy Atom Count: 23
• Complexity: 392

Purity/Quality:

99% ^*data from raw suppliers

Nonanal 2,4-dinitrophenylhydrazone analytical standard ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCCCC=NNC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-]
• Isomeric SMILES: CCCCCCCC/C=N/NC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of 2,4-Dinitrophenylhydrazone nonanal

There total 14 articles about 2,4-Dinitrophenylhydrazone nonanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trioleoylglycerol (122-32-7) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → 2-undecenal (53448-07-0,71277-05-9,2463-77-6) + heptanal 2,4-dinitrophenylhydrazone (2074-05-7) + Δ2-Decenal-(2,4-dinitro-phenylhydrazon) (4237-03-0) + decanal (2,4-dinitrophenyl)hydrazone (1527-95-3) + 1-(hexylidene)-2-(2,4-dinitrophenyl)hydrazine (1527-97-5) + octanal (2,4-dinitrophenyl)hydrazone (1726-77-8) + nonanal (2,4-dinitrophenyl)hydrazone (2348-19-8,74335-75-4,74335-76-5)

Guidance literature:

trioleoylglycerol; With air; at 120 ℃; for 10h;

(2,4-dinitro-phenyl)-hydrazine; In acetonitrile; for 1h; Darkness;

DOI:10.1007/s00706-017-2036-3

Reference yield:

(R,7E,16Z)-pentacosa-7,16-dien-2,4-diyne-1,6-diol (862672-34-2) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → nonanal (2,4-dinitrophenyl)hydrazone (2348-19-8,74335-75-4,74335-76-5)

Guidance literature:

(R,7E,16Z)-pentacosa-7,16-dien-2,4-diyne-1,6-diol; With osmium(VIII) oxide; H₅IO₄; acetic acid; In water; tert-butyl alcohol; at 20 ℃; for 1.33333h;

(2,4-dinitro-phenyl)-hydrazine; In tert-butyl alcohol; at 20 ℃; for 0.5h; Further stages.;

DOI:10.1021/np040233u

Reference yield:

Dihydroxystearic Acid (120-87-6) → nonanal (2,4-dinitrophenyl)hydrazone (2348-19-8,74335-75-4,74335-76-5)

Guidance literature:

Multi-step reaction with 2 steps

1: ethanol; periodic acid; H₂SO₄

With ethanol; sulfuric acid; periodic acid;

upstream raw materials:

nonan-1-al

(2,4-dinitro-phenyl)-hydrazine

pelargonaldehyde diethyl acetal

2-octyl-1,3-dioxolane

Downstream raw materials:

C₁₅H₂₁BrN₄O₄

Refernces

• 1、 Watanabe, Kinzo,Tsuda, Yuichiro,Hamada, Maki,Omori, Miki,Mori, Go,Iguchi, Kazuo,Naoki, Hideo,Fujita, Tsuyoshi,Van Soest, Rob W. M.. "Acetylenic strongylodiols from a Petrosia (Strongylophora) Okinawan marine sponge". . p. 1001 - 1005. Retrieved 2008/09/17.