Dimethyl bromomalonate

Base Information Edit

Chemical Name:Dimethyl bromomalonate
CAS No.:868-26-8
Molecular Formula:C5H7BrO4
Molecular Weight:211.012
Hs Code.:29171900
European Community (EC) Number:212-775-4
NSC Number:175888
UNII:D2V5M6E7E6
DSSTox Substance ID:DTXSID60235811
Nikkaji Number:J195.138F
Wikidata:Q83117712
Mol file:868-26-8.mol

Synonyms:Dimethyl bromomalonate;868-26-8;Dimethyl 2-bromomalonate;dimethyl 2-bromopropanedioate;Propanedioic acid, bromo-, dimethyl ester;1,3-dimethyl 2-bromopropanedioate;2-Bromo dimethyl malonate;D2V5M6E7E6;EINECS 212-775-4;NSC-175888;C5H7BrO4;dimethylbromomalo-nate;dimethyl-2-bromomalonate;Dimethyl 2-bromomalonate #;UNII-D2V5M6E7E6;Propanedioic acid, 2-bromo-, 1,3-dimethyl ester;SCHEMBL690839;C5-H7-Br-O4;Bromomalonic Acid Dimethyl Ester;DTXSID60235811;2-Bromomalonic acid dimethyl ester;MFCD00025865;NSC175888;DIMETHYL .ALPHA.-BROMOMALONATE;AKOS015900202;AM81029;NSC 175888;BS-44081;BB 0258966;D3887;FT-0625038;MALONIC ACID, BROMO-, DIMETHYL ESTER;Dimethyl bromomalonate, technical grade, 90%;D78444;J-640358;J-800362

Suppliers and Price of Dimethyl bromomalonate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Dimethyl bromomalonate
500mg
$ 75.00

TCI Chemical
Dimethyl Bromomalonate >95.0%(GC)
5g
$ 38.00

TCI Chemical
Dimethyl Bromomalonate >95.0%(GC)
25g
$ 120.00

Sigma-Aldrich
Dimethyl bromomalonate technical grade, 90%
25ml
$ 192.00

Sigma-Aldrich
Dimethyl bromomalonate technical grade, 90%
5ml
$ 47.40

Crysdot
Dimethyl2-bromomalonate 97%
500g
$ 936.00

Biosynth Carbosynth
Dimethyl Bromomalonate
5 g
$ 100.00

Biosynth Carbosynth
Dimethyl Bromomalonate
10 g
$ 150.00

Biosynth Carbosynth
Dimethyl Bromomalonate
100 g
$ 700.00

Biosynth Carbosynth
Dimethyl Bromomalonate
50 g
$ 400.00

Total 28 raw suppliers

Chemical Property of Dimethyl bromomalonate Edit

Chemical Property:

Appearance/Colour:clear colorless to light yellow liquid
Vapor Pressure:0.0627mmHg at 25°C
Refractive Index:n20/D 1.460(lit.)
Boiling Point:231.32 °C at 760 mmHg
PKA:9.25±0.46(Predicted)
Flash Point:64.689 °C
PSA：52.60000
Density:1.604 g/cm³
LogP:0.09590
XLogP3:1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:209.95277
Heavy Atom Count:10
Complexity:129

Purity/Quality:

98% ^*data from raw suppliers

Dimethyl bromomalonate ^*data from reagent suppliers

Safty Information:

Pictogram(s): C
Hazard Codes:C
Statements: 34-37
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C(C(=O)OC)Br
Uses Dimethyl bromomalonate may be used in the enantioselective synthesis of nitrocyclopropanes.

Technology Process of Dimethyl bromomalonate

There total 8 articles about Dimethyl bromomalonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 108-59-8
malonic acid dimethyl ester

: 868-26-8
dimethyl 2-bromomalonate

Guidance literature:: With ammonium cerium(IV) nitrate; at 25 - 28 ℃; for 3h;
DOI:10.1071/CH07061

Reference yield:

: 108-59-8
malonic acid dimethyl ester

: 37167-59-2
dimethyl dibromomalonate

: 868-26-8
dimethyl 2-bromomalonate

Guidance literature:: With N-Bromosuccinimide; ethyl 2-methyl-1H-indole-3-carboxylate; In n-heptane; at 25 ℃; for 18h; Overall yield = 90 percentSpectr.; Darkness;
DOI:10.1016/j.tetlet.2020.151772