N,N,N',N',N'',N''-Hexaethylboranetriamine

Base Information

• Chemical Name: N,N,N',N',N'',N''-Hexaethylboranetriamine
• CAS No.: 867-97-0
• Molecular Formula: C12H30BN3
• Molecular Weight: 227.201
• DSSTox Substance ID: DTXSID30416099
• Nikkaji Number: J2.103.903I
• Wikidata: Q82225265
• Mol file: 867-97-0.mol

Synonyms:N,N,N',N',N'',N''-Hexaethylboranetriamine;867-97-0;N-[bis(diethylamino)boranyl]-N-ethylethanamine;Boranetriamine, hexaethyl-;Tris(diethylamino) boron;tris-(diethylamino)-borane;SCHEMBL4271846;AMY5794;DTXSID30416099;CS3403;InChI=1/C12H30BN3/c1-7-14(8-2)13(15(9-3)10-4)16(11-5)12-6/h7-12H2,1-6H

Chemical Property of N,N,N',N',N'',N''-Hexaethylboranetriamine

Chemical Property:

• PSA: 9.72000
• LogP: 1.99670
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 9
• Exact Mass: 227.2532781
• Heavy Atom Count: 16
• Complexity: 126

Purity/Quality:

98%,99%, ^*data from raw suppliers

N,N,N',N',N'',N''-Hexaethylboranetriamine 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(N(CC)CC)(N(CC)CC)N(CC)CC

Technology Process of N,N,N',N',N'',N''-Hexaethylboranetriamine

There total 8 articles about N,N,N',N',N'',N''-Hexaethylboranetriamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

Bis(diethylamino)(trimethylstannyl)boran (79812-14-9) + tert-butyl alcohol (75-65-0) → tri-(tert-butyl)borate (7397-43-5) + tris(diethylamino)borane (867-97-0) + trimethylstannane (1631-73-8)

Guidance literature:

equimolar amt. of educt, t-BuOH dropped to B(NEt2)2Sn(CH3)3 at -30°C, stirred;

Reference yield:

dimethyl-amine; compound with boron chloride (856314-21-1) + dimethyl amine (124-40-3) → dichlorodimethylaminoborane (1113-31-1) + chloro-bis(dimethylamino)borane (6562-41-0) + tris(diethylamino)borane (867-97-0) + N,N-dimethylammonium chloride (506-59-2)

Guidance literature:

with NHMe2 excess;

Reference yield:

dichlorodimethylaminoborane (1113-31-1) + ethylamine (75-04-7,85404-22-4) → (BNHC2H5NC2H5)3 + tris(dimethylamino)borane (4375-83-1) + tris(diethylamino)borane (867-97-0) + ethanamine hydrochloride (557-66-4)

Guidance literature:

In Petroleum ether;

DOI:10.1039/JR9650001511

upstream raw materials:

diethylamine

dichlorodimethylaminoborane

ethylamine

dimethyl-amine; compound with boron chloride

Downstream raw materials:

diethyl amine hydrochloride

Diethylaminodichloroborane

1,3-dimethyl-2-diethylamino-1,3,2-diazaboracyclohexane

(BN(C₆H₅)CH₂CH₂N)3

Refernces

• 1、 Chavant, P. Y.,Vaultier, M.. "Preparation of some organo-bis(diisopropylamino)boranes and their application to the synthesis of oxazaborolidines". . p. 37 - 46. Retrieved 2007/10/02.