Boranediamine, 1-chloro-N,N,N',N'-tetraethyl-

Base Information

• Chemical Name: Boranediamine, 1-chloro-N,N,N',N'-tetraethyl-
• CAS No.: 868-25-7
• Molecular Formula: C8H20BClN2
• Molecular Weight: 190.524
• DSSTox Substance ID: DTXSID40416106
• Nikkaji Number: J1.279.726E
• Wikidata: Q82225277
• Mol file: 868-25-7.mol

Synonyms:Boranediamine, 1-chloro-N,N,N',N'-tetraethyl-;868-25-7;bis(diethylamino)chloroborane;SCHEMBL4269011;DTXSID40416106;InChI=1/C8H20BClN2/c1-5-11(6-2)9(10)12(7-3)8-4/h5-8H2,1-4H

Chemical Property of Boranediamine, 1-chloro-N,N,N',N'-tetraethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 190.1408065
• Heavy Atom Count: 12
• Complexity: 93.2

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(N(CC)CC)(N(CC)CC)Cl

Technology Process of Boranediamine, 1-chloro-N,N,N',N'-tetraethyl-

There total 1 articles about Boranediamine, 1-chloro-N,N,N',N'-tetraethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethyl-amine; compound with boron chloride + diethylamine (109-89-7) → bis(diethylamino)boron chloride (868-25-7) + tris(diethylamino)borane (867-97-0) + diethyl amine hydrochloride (660-68-4) + Diethylaminodichloroborane (868-30-4)

Guidance literature:

Reference yield: 98.0%

bis(diethylamino)boron chloride (868-25-7) + dibutyl-bis-phenylethynyl-silane → ((HO)2B)2C4Si(C4H9)2(C6H5)2 (279241-31-5)

Guidance literature:

With hydrogenchloride; naphthalen-1-yl-lithium; In tetrahydrofuran; under Ar; THF soln. of a mixt. of Li and naphthaline stirred at room temp. for 4 h; addn. of THF soln. of Si compound; dropwise addn. of THF soln. of BCl(NEt2)2 at -78°C; mixt. allowed to warm to room temp. over 6 h; removal of solvents; addn. of Et2O; filtered; addn. of 1N HCl to filtrate; extraction with Et2O several times; combined org. phases washed with brine, dried over Na2SO4, filtered and concd.; residue dissolved in Et2Oand pptd. with hexane;

DOI:10.1002/(SICI)1521-3773(20000502)39:9<1695::AID-ANIE1695>3.0.CO;2-O

Reference yield: 78.0%

bis(diethylamino)boron chloride (868-25-7) + 4-tercbutyl-cyclohexanone (98-53-3) → (CH3)3CC6H8OB(N(C2H5)2)2 (959925-30-5)

Guidance literature:

With potassium hexamethyldisilazane; In tetrahydrofuran; byproducts: KCl; under Ar atm. to soln. KHDMS in THF ketone in THF was added dropwise at 0°C for 30 min, soln. chlorobis(dialkylamino)borane in THF was added and stirred at room temp. for 2 h; soln. was cenrifugated, ppt. was filtered, volatiles were removed in vacuo;

DOI:10.1021/om700676w

upstream raw materials:

diethylamine

Downstream raw materials:

C₁₆H₂₆BCl₂N₃O

C₁₆H₂₇BClN₃O

Bis-diethylamino-(cyclohex-1-enylethinyl)-bor

Bis-diethylamino-phenylethinyl-bor