Cyclohexene, 1-(2-propenyl)-

Base Information

• Chemical Name: Cyclohexene, 1-(2-propenyl)-
• CAS No.: 13511-13-2
• Molecular Formula: C9H14
• Molecular Weight: 122.21
• Hs Code.: 2902199090
• DSSTox Substance ID: DTXSID90159258
• Nikkaji Number: J721.288G
• Wikidata: Q83027573
• Mol file: 13511-13-2.mol

Synonyms:1-prop-2-enylcyclohexene;Cyclohexene, 1-(2-propenyl)-;1-ALLYLCYCLOHEXENE;13511-13-2;1-Allyl-1-cyclohexene;Cyclohexene,1-(2-propenyl)-;1-Allylcyclohexene-1;1-allylcyclohex-1-ene;DTXSID90159258;GTUOTYSUNDPMPS-UHFFFAOYSA-N;AKOS006284913

Chemical Property of Cyclohexene, 1-(2-propenyl)-

Chemical Property:

• Vapor Pressure: 4.05mmHg at 25°C
• Refractive Index: 1.4765
• Boiling Point: 154.6°Cat760mmHg
• Flash Point: 31.3°C
• PSA: 0.00000
• Density: 0.831g/cm³
• LogP: 3.06290
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 122.109550447
• Heavy Atom Count: 9
• Complexity: 120

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCC1=CCCCC1

Technology Process of Cyclohexene, 1-(2-propenyl)-

There total 11 articles about Cyclohexene, 1-(2-propenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

1-allyl-2,8,9-trioxa-5-aza-1-silabicyclo<3.3.3>undecane (92085-71-7) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → 1-allyl-1-cyclohexanol (1123-34-8) + 1-allylcyclohexene (13511-13-2)

Guidance literature:

With titanium tetrachloride; In dichloromethane; at 70 ℃; for 20h;

DOI:10.1016/0022-328X(87)80257-7

Reference yield: 50.0%

allyl bromide (106-95-6) + 2-Chlorocyclohexanone (822-87-7) → 1-allylcyclohexene (13511-13-2)

Guidance literature:

allyl bromide; With samarium; In tetrahydrofuran; at 20 ℃; for 1.08333h; Inert atmosphere;

2-Chlorocyclohexanone; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

DOI:10.1002/chem.200901927

Reference yield:

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + allyl-trimethyl-silane (762-72-1) → 1-allylcyclohexene (13511-13-2)

Guidance literature:

With indium(III) chloride; chloro-trimethyl-silane; In nitromethane; at 20 ℃; for 24h;

DOI:10.1016/S0040-4020(02)00972-9

upstream raw materials:

1-allyl-1-cyclohexanol

1-chloro-1-allyl-cyclohexane

2-Chlorocyclohexanone

allylmagnesium bromide

Downstream raw materials:

3-(cyclohex-1-en-1-yl)propan-1-ol

dichloro-(3-cyclohex-1-enyl-propyl)-silane

C₁₅H₂₀ClOP

3-phenyl-octahydro-cyclopropa[c]phosphindole 3-oxide

Refernces

• 1、 Onishi, Yoshiyuki,Ito, Takeshi,Yasuda, Makoto,Baba, Akio. "Remarkable enhancement of Lewis acidity of chlorosilane by the combined use of indium(III) chloride". . p. 8227 - 8235. Retrieved 2007/10/03.
• 2、 Ohm, Stefan,Baeuml, Englbert,Mayr, Herbert. "A Versatile Synthesis of 1,4-Dienes: Use of Vinyl Ethers as Vinyl Cation Equivalents". . p. 2785 - 2790. Retrieved 2007/10/02.