Erythrulose

Base Information

• Chemical Name: Erythrulose
• CAS No.: 40031-31-0
• Deprecated CAS: 35007-64-8
• Molecular Formula: C4H8O4
• Molecular Weight: 120.105
• Hs Code.: 2914400090
• European Community (EC) Number: 443-800-9,609-775-5
• UNII: HS4GKH53PR
• DSSTox Substance ID: DTXSID70862137
• Nikkaji Number: J1.544.967E
• Wikipedia: Erythrulose
• Wikidata: Q27109825
• Mol file: 40031-31-0.mol

Synonyms:erythrulose;erythrulose, (R)-isomer;L-glycero-tetrulose

Chemical Property of Erythrulose

Chemical Property:

• Boiling Point: 349.6 °C at 760 mmHg
• PKA: 12.00±0.20(Predicted)
• Flash Point: 179.4 °C
• PSA: 77.76000
• Density: 1.42g/cm³
• LogP: -2.09900
• XLogP3: -2
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 120.04225873
• Heavy Atom Count: 8
• Complexity: 80.1

Purity/Quality:

99% ^*data from raw suppliers

1,3,4-Trihydroxy-2-butanone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(C(C(=O)CO)O)O
• Uses: 1,3,4-Trihydroxy-2-butanone is used in self tanning products.

Technology Process of Erythrulose

There total 42 articles about Erythrulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

D-threitol (2418-52-2,10030-58-7,188346-77-2,149-32-6) → D-erythrulose (533-50-6,35007-64-8,40031-31-0,496-55-9)

Guidance literature:

With [(neocuproine)Pd(OAc)]₂(OTf)₂; oxygen; In water; acetonitrile; at 25 ℃; for 20h;

DOI:10.1021/ja4008694

Reference yield: 74.0%

meso-erythritol (909878-64-4,10030-58-7,188346-77-2,149-32-6) → D-erythrulose (533-50-6,35007-64-8,40031-31-0,496-55-9) + D-erythronic acid (488-16-4)

Guidance literature:

PtTl; In perchloric acid; water; for 4h; electrocatalytic reaction;

DOI:10.1051/jcp:1999157

Reference yield: 74.0%

meso-erythritol (909878-64-4,10030-58-7,188346-77-2,149-32-6) → D-erythrulose (533-50-6,35007-64-8,40031-31-0,496-55-9) + D-glyceric acid (473-81-4,600-19-1,6000-40-4,28305-26-2,118916-26-0) + D-erythronic acid (488-16-4) + D-erythrose (583-50-6)

Guidance literature:

PtTl; In perchloric acid; water; for 4h; Product distribution; electrocatalytic reaction; also on Pt and on Pt-Pb electrode; oxidation potential varied: 0.45, 0.6, 0.8 V;

DOI:10.1051/jcp:1999157

upstream raw materials:

diazomethane

(R)-2,3-o-isopropylidene-D-glyceroyl chloride

D-erythrose

D-threose

Downstream raw materials:

meso-erythritol

rac-threitol

glycerol

D-threose

Refernces

• 1、 Güner, Samed,Pick, André,Sieber, Volker,Wegat, Vanessa. "Design of a synthetic enzyme cascade for the: In vitro fixation of a C1carbon source to a functional C4sugar". supporting information. p. 6583 - 6590. Retrieved 2021/09/10.
• 2、 Tolborg, S?ren,Meier, Sebastian,Saravanamurugan, Shunmugavel,Fristrup, Peter,Taarning, Esben,Sádaba, Irantzu. "Shape-selective Valorization of Biomass-derived Glycolaldehyde using Tin-containing Zeolites". . p. 3054 - 3061. Retrieved 2016/11/17.