1,1,3-trichloropropane

Base Information

• Chemical Name: 1,1,3-trichloropropane
• CAS No.: 20395-25-9
• Molecular Formula: C3H5Cl3
• Molecular Weight: 147.432
• Hs Code.: 2903199000
• Mol file: 20395-25-9.mol

Synonyms:Propane,1,1,3-trichloro;1,1,3-trichloro-propane;Propane, 1,1,3-trichloro-;1.1.3-Trichlorpropan;

Chemical Property of 1,1,3-trichloropropane

Chemical Property:

• Vapor Pressure: 7.46mmHg at 25°C
• Melting Point: -58.98°C
• Refractive Index: 1.4698
• Boiling Point: 141°Cat760mmHg
• Flash Point: 59.7°C
• PSA: 0.00000
• Density: 1.309g/cm³
• LogP: 2.41900
• Storage Temp.: Refrigerator, under inert atmosphere
• Solubility.: Chloroform, Ethyl Acetate

Purity/Quality:

1,1,3-Trichloropropane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1,1,3-Trichloropropane is a disinfection byproducts in chlorinated drinking water. Also, it is derived from Acrolein (A191200), which is used in the synthesis of acrylic acid.

Technology Process of 1,1,3-trichloropropane

There total 6 articles about 1,1,3-trichloropropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

cyclopropane (75-19-4) → 1,1,3-trichloropropane (20395-25-9) + 1,2,3-trichloropropane (96-18-4) + cyclopropyl chloride (7393-45-5) + 1,1-dichlorocyclopropane (2088-35-9) + 1,3-Dichloropropane (142-28-9)

Guidance literature:

With chlorine; In trichlorofluoromethane; at 21 ℃; for 0.0833333h; Product distribution; Mechanism; Irradiation; also 1,3-dichloropropane; var. solvents (also in the gas phase);

DOI:10.1021/ja00091a020

Reference yield:

phosphorus pentachloride (10026-13-8,874483-75-7) + acrolein (107-02-8,25068-14-8) → E/Z-1,3-Dichloropropene (542-75-6) + 1,1,3-trichloropropane (20395-25-9) + 3,3-dichloropropene (563-57-5)

Guidance literature:

Reference yield:

1,1,1,3-tetrachloropropane (1070-78-6) + phenylsilane (694-53-1) → 1,1,3-trichloropropane (20395-25-9) + dichlorophenylsilane (1631-84-1) + phenylchlorosilane (4206-75-1)

Guidance literature:

With NbCl₃(N,N′-bis-(2,6-diisopropylphenyl)-1,4-diaza-2,3-dimethyl-1,3-butadiene); In benzene-d6; at 120 ℃; for 2h; Reagent/catalyst;

DOI:10.1039/c9cc03268a

upstream raw materials:

cyclopropane

phosphorus pentachloride

acrolein

water

Downstream raw materials:

2-(3,3-Dichloro-propyl)-isothiourea; hydrochloride

1,3-Dichloropropane

1,1-dichloro-3-bromopropane

Benzoic acid 3,3-dichloro-propyl ester

Refernces

• 1、 Tanko, James M.,Suleman, N. Kamrudin. "Solvent pressure effects in free radical reactions. 2. Reconciliation of the gas and condensed phase chlorination of cyclopropane". . p. 5162 - 5166. Retrieved 2007/10/02.