2,4,5-TRIMETHYLBENZYL ALCOHOL

Base Information

• Chemical Name: 2,4,5-TRIMETHYLBENZYL ALCOHOL
• CAS No.: 4393-05-9
• Molecular Formula: C10H14O
• Molecular Weight: 150.221
• Hs Code.: 2906299090
• Mol file: 4393-05-9.mol

Synonyms:2,4,5-Trimethylbenzyl alcohol;Benzyl alcohol,2,4,5-trimethyl;2,4,5-Trimethyl-benzylalkohol;Benzenemethanol, 2,4,5-trimethyl-;Benzenemethanol,2,4,5-trimethyl;2.4.5-Trimethyl-1-hydroxymethyl-benzol;2,4,5-trimethyl-benzenemethanol;11-Oxy-1.2.4.5-tetramethyl-benzol;

Chemical Property of 2,4,5-TRIMETHYLBENZYL ALCOHOL

Chemical Property:

• PSA: 20.23000
• LogP: 2.10410

Purity/Quality:

95% ^*data from raw suppliers

(2,4,5-Trimethylphenyl)methanol 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4,5-TRIMETHYLBENZYL ALCOHOL

There total 19 articles about 2,4,5-TRIMETHYLBENZYL ALCOHOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,4,5-trimethylbenzaldehyde (5779-72-6) → 2,4,5-trimethyl-benzyl alcohol (4393-05-9)

Guidance literature:

With sodium tetrahydroborate; In ethanol; at 20 ℃; for 16h; Inert atmosphere;

DOI:10.1002/chem.201404139

Reference yield: 75.0%

1,2,4,5-tetramethylbenzene (95-93-2) → 2,4,5-trimethylbenzaldehyde (5779-72-6) + 2,4,5-trimethyl-benzyl alcohol (4393-05-9)

Guidance literature:

With sulfuric acid; water; oxygen; 9-(2-mesityl)-10-methylacridinium perchlorate; In acetonitrile; for 1.33333h; Reagent/catalyst; Quantum yield; Irradiation;

DOI:10.1039/b920606j

Reference yield: 70.0%

1,3,6,8-tetra-n-butylpyrimido<5,4-g>pteridine-2,4,5,7(1H,3H,6H,8H)-tetrone 10-oxide (33070-58-5) + 1,2,4,5-tetramethylbenzene (95-93-2) → 2,4,5-trimethylbenzaldehyde (5779-72-6) + 2,4,5-trimethyl-benzyl alcohol (4393-05-9)

Guidance literature:

at 135 ℃; for 2h;

DOI:10.1248/cpb.39.195

upstream raw materials:

acetic acid 2,4,5-trimethyl-benzyl ester

2,4,5-trimethylbenzyl chloride

4.5-Dimethyl-2-tetrahydropyranyl-⁽²⁾-oxymethyl-cyclohexadien-(1.4)-carbaldehyd-⁽¹⁾

1,2,4,5-tetramethylbenzene

Downstream raw materials:

(2,4,5-trimethyl-phenyl)-acetonitrile

(2,4,5-trimethyl-phenyl)-acetic acid

(2,4,5-trimethyl-3,6-dinitro-phenyl)-acetic acid

1-(Bromomethyl)-2,4,5-trimethylbenzene

Refernces

• 1、 Michelet, Bastien,Bour, Christophe,Gandon, Vincent. "Gallium-assisted transfer hydrogenation of alkenes". supporting information. p. 14488 - 14492. Retrieved 2015/04/16.
• 2、 Yoshino, Yasushi,Hayashi, Yoshiaki,Iwahama, Takahiro,Sakaguchi, Satoshi,Ishii, Yasutaka. "Catalytic Oxidation of Alkylbenzenes with Molecular Oxygen under Normal Pressure and Temperature by N-Hydroxyphthalimide Combined with Co(OAc)2". . p. 6810 - 6813. Retrieved 2007/10/03.