Azidocyclopentane

Base Information

• Chemical Name: Azidocyclopentane
• CAS No.: 33670-50-7
• Molecular Formula: C5H9N3
• Molecular Weight: 111.147
• Hs Code.: 2929909090
• NSC Number: 30439
• UNII: 6NV75D25WG
• DSSTox Substance ID: DTXSID50187350
• Nikkaji Number: J376.593H
• Wikidata: Q83059024
• Mol file: 33670-50-7.mol

Synonyms:Azidocyclopentane;Cyclopentyl azide;33670-50-7;Cyclopentane, azido-;NSC-30439;6NV75D25WG;LCZC3520;SCHEMBL13512643;DTXSID50187350;SSJIACUDWJVGLB-UHFFFAOYSA-N;NSC30439;NSC 30439;AKOS010631281;EN300-100805;F79502

Chemical Property of Azidocyclopentane

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 49.75000
• Density: g/cm³
• LogP: 1.69206
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 111.079647300
• Heavy Atom Count: 8
• Complexity: 109

Purity/Quality:

99% ^*data from raw suppliers

Azidocyclopentane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(C1)N=[N+]=[N-]

Technology Process of Azidocyclopentane

There total 2 articles about Azidocyclopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclopentene (142-29-0) → cyclopentyl azide (33670-50-7) + cyclopentyl acetate (933-05-1)

Guidance literature:

With lead(IV) acetate; trimethylsilylazide; diborane; Yield given. Multistep reaction. Yields of byproduct given; 1) THF, 2) CH₂Cl₂, -25 degC, 4 h, then -25 degC to r.t., 2 h, then r.t., 4 h;

DOI:10.1246/bcsj.57.1026

Reference yield:

lead(IV) tetraacetate (546-67-8) + cyclopentene (142-29-0) → cyclopentyl azide (33670-50-7) + cyclopentyl acetate (933-05-1)

Guidance literature:

With trimethylsilylazide; diborane; Yield given. Multistep reaction. Yields of byproduct given; 1) THF, 2) CH₂Cl₂, -25 degC, 4 h, then -25 degC to r.t., 2 h, then r.t., 4 h;

DOI:10.1246/bcsj.57.1026

Reference yield: 95.0%

cyclopentyl azide (33670-50-7) → nitrocyclopentane (2562-38-1)

Guidance literature:

With HOF* CH₃CN; In chloroform; at 0 ℃; for 0.00138889h;

DOI:10.1021/jo060440u

upstream raw materials:

lead(IV) tetraacetate

cyclopentene

Downstream raw materials:

Cyclopentamine

1-(1-phenylethyl)piperidine

2,3,4,5-tetrahydropyridine

cyclopentanone

Refernces