Methanediol, phenyl-, acetate formate

Base Information

• Chemical Name: Methanediol, phenyl-, acetate formate
• CAS No.: 113388-44-6
• Molecular Formula: C10H10O4
• Molecular Weight: 194.187
• Mol file: 113388-44-6.mol

Synonyms:

Chemical Property of Methanediol, phenyl-, acetate formate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanediol, phenyl-, acetate formate

There total 5 articles about Methanediol, phenyl-, acetate formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

1-Phenylbut-1-en-3-one (122-57-6) → (formyloxy)(acetoxy)phenylmethane (113388-44-6)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In toluene; at 20 ℃; for 24h;

DOI:10.1021/acs.orglett.7b02382

Reference yield: 76.0%

formic acid (64-18-6) + α-Chlorobenzyl acetate (26827-40-7) → (formyloxy)(acetoxy)phenylmethane (113388-44-6)

Guidance literature:

With triethylamine; In acetone; at 20 ℃; for 3h;

DOI:10.1021/acs.orglett.7b02382

Reference yield: 8.0%

1-phenyl-2-formyloxypropene (113388-43-5) → Formic acid 2-oxo-1-phenyl-propyl ester (42523-74-0) + (formyloxy)(acetoxy)phenylmethane (113388-44-6) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

With dihydrogen peroxide; bis(o-nitrophenyl) diselenide; In dichloromethane; for 72h; Ambient temperature;

DOI:10.1016/S0040-4020(01)86890-3

upstream raw materials:

1-phenyl-2-formyloxypropene

α-methyl-trans-cinnamaldehyde

1-Phenylbut-1-en-3-one

benzaldehyde

Downstream raw materials:

N-benzylformamide

N-benzylidene benzylamine

N-(furan-2-ylmethyl)formamide

N_b-formyltryptamine

Refernces

• 1、 Syper, Ludwik. "REACTION OF α,β-UNSATURATED ALDEHYDES WITH HYDROGEN PEROXIDE CATALYSED BY BENZENESELENINIC ACIDS AND THEIR PRECURSORS". . p. 2853 - 2872. Retrieved 2007/10/02.