CID 6336261

Base Information

• Chemical Name: CID 6336261
• CAS No.: 13818-89-8
• Molecular Formula: Ge2H6
• Molecular Weight: 151.228
• European Community (EC) Number: 630-780-3
• DSSTox Substance ID: DTXSID801030397
• Nikkaji Number: J95.351B
• Mol file: 13818-89-8.mol

Synonyms:13818-89-8;$l^{3};CID 15919811;CID 6336261;DTXSID801030397;AKOS015915860

Chemical Property of CID 6336261

Chemical Property:

• Melting Point: -109°C
• Boiling Point: 31°C
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -0.08660
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 151.8902038
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Hazard Codes: F+,Xn
• Statements: 12-20/21/22-36/37/38
• Safety Statements: 16-24-26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [GeH3].[GeH3]

Technology Process of CID 6336261

There total 13 articles about CID 6336261 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 1.0%

tetracarbonyldigermanylcobalt (69480-70-2) + mercury dichloride → chlorogermane (13637-65-5) + digermane (13818-89-8) + bis(tetracarbonylcobalt)mercury (13964-88-0) + digermanyl chloride (13825-03-1)

Guidance literature:

In neat (no solvent); drawing Co-complex through HgCl2; collection at -196°C, fractionation;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + Ge(x)Mg(1-x) → germane (7782-65-2) + digermane (13818-89-8) + trigermane (14691-44-2)

Guidance literature:

In not given; reaction of diluted HCl (1 : 4) with Ge Mg alloy in H2 atmosphere;; condensing and fractionating in a Stock apparatus; transition temperature : -63 - -60 °C;;

DOI:10.1021/ja01668a015

Reference yield:

germanium (7440-56-4) + hydrogen (1333-74-0) → germane (7782-65-2) + digermane (13818-89-8) + (GeH2)2 + germyl anion

Guidance literature:

In neat (no solvent); co-depositon laser-ablated Ge with H2 at 3.5 K; other products - GeH, GeH2, GeH3, Ge2H2; identified by IR spectroscopy;

DOI:10.1021/ja029862l

upstream raw materials:

monogermylphosphane

hydrogen sulfide

germane

methanol

Downstream raw materials:

germanium

germane

iso-tetragermane

Refernces

• 1、 Wang, Xuefeng,Andrews, Lester. "Infrared spectra of group 14 hydrides in solid hydrogen: Experimental observation of Pbh4, Pb2H2, and Pb2H4". . p. 6581 - 6587. Retrieved 2007/10/03.