Tetrabutylammonium formate

Base Information

• Chemical Name: Tetrabutylammonium formate
• CAS No.: 35733-58-5
• Molecular Formula: C17H37NO2
• Molecular Weight: 287.486
• Hs Code.: 2923900090
• European Community (EC) Number: 252-704-4
• DSSTox Substance ID: DTXSID70189275
• Mol file: 35733-58-5.mol

Synonyms:Tetrabutylammonium formate;35733-58-5;tetrabutylazanium;formate;EINECS 252-704-4;tetrabutylazanium,formate;SCHEMBL105861;C16H36N.CHO2;DTXSID70189275;C16-H36-N.C-H-O2

Chemical Property of Tetrabutylammonium formate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 40.13000
• Density: g/cm³
• LogP: 4.00560
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 287.282429423
• Heavy Atom Count: 20
• Complexity: 124

Purity/Quality:

98%Min ^*data from raw suppliers

TETRABUTYLAMMONIUM FORMATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.C(=O)[O-]

Technology Process of Tetrabutylammonium formate

There total 2 articles about Tetrabutylammonium formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

formic acid (64-18-6) + tetra(n-butyl)ammonium hydroxide (2052-49-5) → tetra(n-butyl)ammonium formate (35733-58-5)

Guidance literature:

In water; pH=Ca. 8.45; Glovebox;

DOI:10.1021/ja501051s

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + tetrabutylammonium tetrafluoroborate (429-42-5) → 1-butylene (106-98-9,9003-28-5) + tributyl-amine (102-82-9) + tetra(n-butyl)ammonium formate (35733-58-5)

Guidance literature:

With triangular rhodium complex * (BPh₄)2; In acetonitrile; Yield given; electrochemical reduction;

DOI:10.1246/cl.1994.2175

Reference yield: 100.0%

tetra(n-butyl)ammonium formate (35733-58-5) + (Z)-(1RS,3SR,4SR,5SR)-4-<7-<(methanesulfonyl)oxy>-2-heptenyl>-5-<1-(4-methoxyphenyl)non-2-ynylthio>-2-thiabicyclo<3.1.0>hexane (106470-32-0) → Formic acid (Z)-7-{(1R,2R,3R,5S)-3-[1-(4-methoxy-phenyl)-non-2-ynylsulfanyl]-6-thia-bicyclo[3.1.0]hex-2-yl}-hept-5-enyl ester (106470-33-1)

Guidance literature:

In N,N-dimethyl-formamide; at 60 ℃; for 2h;

DOI:10.1021/jo00381a027

upstream raw materials:

formic acid

tetra(n-butyl)ammonium hydroxide

carbon dioxide

tetrabutylammonium tetrafluoroborate

Downstream raw materials:

Formic acid (Z)-7-{(1R,2R,3R,5S)-3-[1-(4-methoxy-phenyl)-non-2-ynylsulfanyl]-6-thia-bicyclo[3.1.0]hex-2-yl}-hept-5-enyl ester

2-methyl-2-(2-phenylethyl)but-3-enoic acid

Methyl-2-(3-chlorophenyl) propanoate

4-(1-methoxycarbonyl-ethyl)-benzoic acid methyl ester

Refernces

• 1、 Grills, David C.,Farrington, Jaime A.,Layne, Bobby H.,Lymar, Sergei V.,Mello, Barbara A.,Preses, Jack M.,Wishart, James F.. "Mechanism of the formation of a Mn-based CO2 reduction catalyst revealed by pulse radiolysis with time-resolved infrared detection". . p. 5563 - 5566. Retrieved 2014.
• 2、 Martin, Kerli,N?ges, Juuli,Haav, Kristjan,Kadam, Sandip A.,Pung, Astrid,Leito, Ivo. "Exploring Selectivity of 22 Acyclic Urea-, Carbazole- and Indolocarbazole-Based Receptors towards 11 Monocarboxylates". . p. 5231 - 5237. Retrieved 2017/09/29.