Silane, trimethyl-2-propynyl-

Base Information Edit

Chemical Name:Silane, trimethyl-2-propynyl-
CAS No.:13361-64-3
Molecular Formula:C6H12 Si
Molecular Weight:112.247
Hs Code.:29310099
European Community (EC) Number:236-427-6
UNII:L8BVJ8DGN6
DSSTox Substance ID:DTXSID6065426
Nikkaji Number:J213.873E
Wikidata:Q72514331
Mol file:13361-64-3.mol

Synonyms:13361-64-3;PROPARGYLTRIMETHYLSILANE;Silane, trimethyl-2-propynyl-;trimethyl(prop-2-ynyl)silane;trimethyl(prop-2-yn-1-yl)silane;Trimethyl(propargyl)silane;Trimethyl(2-propynyl)silane;Propargyltrimethylsilane, tech grade;Silane, trimethyl-2-propyn-1-yl-;2-Propynyltrimethylsilane;L8BVJ8DGN6;Trimethyl-2-propynylsilane;EINECS 236-427-6;2-Propynyl-trimethylsilane;MFCD00042922;propargyl trimethylsilane;UNII-L8BVJ8DGN6;trimethyl-prop-2-ynyl-silane;3-(trimethylsilyl)-1-propyne;Trimethyl(2-propynyl)silane #;DTXSID6065426;AMY6982;AKOS028108304;AS-49419;CS-0187708;FT-0601921;I10158;A935368;J-006419;Trimethyl(propargyl)silane contains 500?ppm bht as stabilizer;Trimethyl(propargyl)silane, contains 500 ppm BHT as stabilizer

Suppliers and Price of Silane, trimethyl-2-propynyl-

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Trimethyl(propargyl)silane contains 500 ppm BHT as stabilizer
1g
$ 180.00

American Custom Chemicals Corporation
3-(TRIMETHYLSILYL) PROPYNE 95.00%
1G
$ 716.13

Total 37 raw suppliers

Chemical Property of Silane, trimethyl-2-propynyl- Edit

Chemical Property:

Vapor Pressure:67.2mmHg at 25°C
Melting Point:148-151 °C(Solv: ethyl ether (60-29-7))
Refractive Index:n20/D 1.413(lit.)
Boiling Point:89°Cat760mmHg
Flash Point:°C
PSA：0.00000
Density:0.763g/cm³
LogP:1.95780
Storage Temp.:−20°C
Solubility.:sol ether, THF, CH2Cl2.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:112.070826917
Heavy Atom Count:7
Complexity:88.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trimethyl(propargyl)silane contains 500 ppm BHT as stabilizer ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,Xi
Statements: 11-36/37/38
Safety Statements: 16-26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)CC#C
Physical properties bp 91–93 °C/760 mmHg; 40 °C/140 mmHg; d 0.753 g mL?1; nD 20 1.4140.
Uses 3-Trimethylsilyl-1-propyne is used as propargylation agent; allenylation agent; can give addition reactions on the triple bond. It takes part in the following reactions: Propargylation Reactions, Alkylation Reactions, Reactions with Epoxides,Reactions with Aldehydes and Ketones, Reactions with Chloroformates, Reactions with Polyoxymethylene and Amines, Allenylation Reactions, Substitution Reactions, Reactions with Acetals and Hemiacetals, Reactions with Aldehydes and Ketones, Reactions with in situ Generated Iminium and α-Acyl Iminium Ions, Reactions with Acid Chlorides, Reactions with Conjugated Heteroatomic Systems, Reactions of the Triple Bond etc. Trimethyl(propargyl)silane is suitable for use in the synthesis of diverse end-functionalized (ω-carboxyl, ω-hydroxy, ω-methyl-vinyl, ω-trimethylsilane, and ω-glycidyl-ether) via ′′click′′ reaction. It may be used in the synthesis of γ-allenyl-GABA (γ-aminobutyric acid), via Lewis acid mediated reaction with ω-ethoxy lactams.

Technology Process of Silane, trimethyl-2-propynyl-

There total 10 articles about Silane, trimethyl-2-propynyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%