N,N-dimethyl-O-ethylthiocarbamate platinum(II)

Base Information

• Chemical Name: N,N-dimethyl-O-ethylthiocarbamate platinum(II)
• CAS No.: 73804-56-5
• Molecular Formula: C₁₀H₂₂Cl₂N₂O₂PtS₂
• Molecular Weight: 532.415
• Mol file: 73804-56-5.mol

Synonyms:Carbamothioicacid, dimethyl-, O-ethyl ester, platinum complex; cis-Dichlorobis(O-ethylN,N-dimethylthiocarbamate)platinum

Chemical Property of N,N-dimethyl-O-ethylthiocarbamate platinum(II)

Chemical Property:

• Vapor Pressure: 7.56mmHg at 25°C
• Boiling Point: 135.9°C at 760 mmHg
• Flash Point: 36°C
• PSA: 102.54000
• LogP: 2.57990

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N-dimethyl-O-ethylthiocarbamate platinum(II)

There total 7 articles about N,N-dimethyl-O-ethylthiocarbamate platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-dichlorobis(N,N-dimethyl O-ethylthiocarbamate)platinum(II) (73797-45-2,73804-56-5) → trans-Pt(N,N-dimethyl O-ethylthiocarbamate)2Cl2 (73804-56-5,73797-45-2)

Guidance literature:

In not given; in soln.;

DOI:10.1016/S0020-1693(00)84169-9

Reference yield:

potassium tetrachloroplatinate(II) (10025-99-7) + N,N-dimethyl ethyl thiocarbamate (17996-38-2) → cis-dichlorobis(N,N-dimethyl O-ethylthiocarbamate)platinum(II) (73797-45-2,73804-56-5)

Guidance literature:

In ethanol; molar ratio Pt : ligand = 1 : 3, room temp., 3 days; evapn. (reduced pressure), drying (vac.), recrystn. (benzene/hexane); elem. anal.;

DOI:10.1016/S0020-1693(00)84169-9

Reference yield:

potassium tetrachloroplatinate(II) (10025-99-7) + N,N-dimethyl ethyl thiocarbamate (17996-38-2) → trans-Pt(N,N-dimethyl O-ethylthiocarbamate)2Cl2 (73804-56-5,73797-45-2)

Guidance literature:

In ethanol; water; molar ratio Pt : ligand = 1 : 1 - 1 : 6; slow crystn. of sepd. oil, drying (vac.), recrystn. (benzene/hexane); elem. anal.;

DOI:10.1016/S0020-1693(00)84169-9

upstream raw materials:

N,N-dimethyl ethyl thiocarbamate

platinum(II) chloride

potassium tetrachloroplatinate(II)

cis-dichlorobis(N,N-dimethyl O-ethylthiocarbamate)platinum(II)

Downstream raw materials:

trans-Pt(N,N-dimethyl O-ethylthiocarbamate)2Cl2