3-Dodecene

Base Information

• Chemical Name: 3-Dodecene
• CAS No.: 2030-83-3
• Molecular Formula: C12H24
• Molecular Weight: 168.323
• Hs Code.: 2901299090
• European Community (EC) Number: 809-714-4
• DSSTox Substance ID: DTXSID901015936
• Nikkaji Number: J97.389K,J97.390D
• Wikidata: Q27160478
• Mol file: 2030-83-3.mol

Synonyms:3-Dodecene;(E)-3-Dodecene;(E)-dodec-3-ene;trans-3-Dodecene;2030-83-3;3-Dodecene, (E)-;(3E)-3-Dodecene;7206-14-6;dodec-3-ene;CHEBI:88589;CHEBI:167553;WLTSXAIICPDFKI-FNORWQNLSA-N;DTXSID901015936;Q27160478

Chemical Property of 3-Dodecene

Chemical Property:

• Vapor Pressure: 0.255mmHg at 25°C
• Melting Point: -38.4°C (estimate)
• Refractive Index: 1.4274 (estimate)
• Boiling Point: 212.2°Cat760mmHg
• Flash Point: 73.7°C
• PSA: 0.00000
• Density: 0.764g/cm³
• LogP: 4.70320
• XLogP3: 5.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 8
• Exact Mass: 168.187800766
• Heavy Atom Count: 12
• Complexity: 92.2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCC=CCC
• Isomeric SMILES: CCCCCCCC/C=C/CC

Technology Process of 3-Dodecene

There total 13 articles about 3-Dodecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

(E/Z)-1,3-dodecadiene → dodecane (112-40-3) + dodec-3-ene (2030-83-3)

Guidance literature:

With 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine cobalt(II) dichloride; hydrogen; sodium triethylborohydride; In toluene; at -78 - 20 ℃; for 5h; under 760.051 Torr;

DOI:10.1021/acscatal.6b02272

Reference yield: 68.0%

nonan-1-al (124-19-6) + n-propyltriphenylphosphonium bromide (6228-47-3) → dodec-3-ene (2030-83-3) + Triphenylphosphine oxide (791-28-6)

Guidance literature:

With water; potassium carbonate; In 1,4-dioxane; at 95 ℃; for 3.5h;

DOI:10.1016/S0040-4020(01)87435-4

Reference yield:

methanol (67-56-1) + Elaidic Acid (112-79-8) + 9,12-octadecadienoic acid (60-33-3,506-21-8,2197-37-7,2420-42-0,2420-55-5,116745-32-5,26085-09-6,64080-88-2,7049-66-3,949900-18-9,60476-23-5,6144-28-1,67922-65-0,89718-18-3) + 1-hexadecylcarboxylic acid (57-10-3) + stearic acid (57-11-4) + 9,12,15-octadecatrienoic acid (463-40-1,1955-33-5,21661-10-9,21661-09-6,21661-13-2,21661-11-0) → octadec-9-enoic acid methyl ester (112-62-9) + methyl 11-dodecenoate (29972-79-0) + hexadecanoic acid methyl ester (112-39-0) + Methyl stearate (112-61-8) + methyl arachidate (1120-28-1) + dodec-3-ene (2030-83-3) + methyl 9-pentadecenoate (25915-47-3) + 1,19-nonadec-9-enedioic acid dimethyl ester (57568-16-8) + C22H40O4 (62402-77-1) + 1,21-heneicos-9-endioic dimethyl ester (1152412-76-4) + 6-pentadecene (42714-72-7) + 5-tridecene + 9-octadecene (5557-31-3) + dimethyl 9-octadecen-1,18-dioate (13481-97-5) + 9-eicosenoic acid methyl ester

Guidance literature:

Elaidic Acid; 9,12-octadecadienoic acid; 1-hexadecylcarboxylic acid; stearic acid; 9,12,15-octadecatrienoic acid; dichloro(tricyclohexylphosphino)(benzylidene)(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)ruthenium(III); at 53 ℃; for 20h; Neat (no solvent);

With ethyl vinyl ether;

methanol; sulfuric acid; Product distribution / selectivity;

upstream raw materials:

1-butylene

octadec-9-enoic acid methyl ester

nonan-1-al

n-propyltriphenylphosphonium bromide

Downstream raw materials:

2-ethyl hexanol ester of hexadecanoic acid

Refernces

• 1、 -. "Method of producing dicarboxylic acids". Page/Page column Sheet 5/6; 11; 12; 14; 18. . Retrieved 2009/05/29.
• 2、 -. "SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES VIA OLEFIN METATHESIS". Page/Page column 41-42; 51. . Retrieved 2008/06/13.