[(Cyclohexylamino)sulfanyl](dimethylamino)methanethione

Base Information

• Chemical Name: [(Cyclohexylamino)sulfanyl](dimethylamino)methanethione
• CAS No.: 52243-24-0
• Molecular Formula: C9H18N2S2
• Molecular Weight: 218.387
• DSSTox Substance ID: DTXSID40506450
• Wikidata: Q82362186
• Mol file: 52243-24-0.mol

Synonyms:52243-24-0;[(Cyclohexylamino)sulfanyl](dimethylamino)methanethione;DTXSID40506450;N-cyclohexyl-S-( N,N-dimethylthiocarbamoyl)-thiohydroxylamine

Chemical Property of [(Cyclohexylamino)sulfanyl](dimethylamino)methanethione

Chemical Property:

• XLogP3: 2.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 218.09114093
• Heavy Atom Count: 13
• Complexity: 165

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)C(=S)SNC1CCCCC1

Technology Process of [(Cyclohexylamino)sulfanyl](dimethylamino)methanethione

There total 4 articles about [(Cyclohexylamino)sulfanyl](dimethylamino)methanethione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

Thiram (137-26-8,93196-73-7) + cyclohexylamine (108-91-8,157973-60-9) → N-cyclohexyl-S-(N,N-dimethylthiocarbamoyl)thiohydroxylamine (52243-24-0) + cyclohexylammonium N,N-dimethyldithiocarbamate

Guidance literature:

at 20 ℃; for 3h;

Reference yield: 78.0%

Thiram (137-26-8,93196-73-7) + cyclohexylamine (108-91-8,157973-60-9) → N-cyclohexyl-N',N'-dimethylthiourea (24070-58-4) + N-cyclohexyl-S-(N,N-dimethylthiocarbamoyl)thiohydroxylamine (52243-24-0) + cyclohexylaminodithiocarboxylic acid, cyclohexylammonium salt (18879-86-2) + cyclohexylammonium N,N-dimethyldithiocarbamate

Guidance literature:

at 20 ℃; for 3h; Further Variations:; Temperatures; Solvents; Product distribution;

DOI:10.1007/BF02498275

Reference yield:

Thiram (137-26-8,93196-73-7) + cyclohexylamine (108-91-8,157973-60-9) → N-cyclohexyl-S-(N,N-dimethylthiocarbamoyl)thiohydroxylamine (52243-24-0)

Guidance literature:

With tetraethylammonium perchlorate; (electrolysis);

DOI:10.1021/jo00410a025

upstream raw materials:

Thiram

cyclohexylamine

Downstream raw materials:

N-cyclohexyl-N',N'-dimethylthiourea

isothiocyanatocyclohexane

1,3-dicyclohexylthiourea

Thiram

Refernces

• 1、 Van Boi, Luu. "Thiocarbamoylation of amine-containing compounds 4. Reactions of tetramethylthiuram disulfide with aliphatic amines". . p. 2294 - 2298. Retrieved 2007/10/03.