N,N-Diethyl-1-naphthylamine

Base Information

• Chemical Name: N,N-Diethyl-1-naphthylamine
• CAS No.: 84-95-7
• Molecular Formula: C14H17N
• Molecular Weight: 199.296
• Hs Code.: 2921450090
• European Community (EC) Number: 201-576-8
• NSC Number: 6340
• UNII: WI5L987JR2
• DSSTox Substance ID: DTXSID7058915
• Nikkaji Number: J134.796I
• Wikidata: Q81988595
• Mol file: 84-95-7.mol

Synonyms:N,N-Diethyl-1-naphthylamine;84-95-7;1-Naphthalenamine, N,N-diethyl-;N,N-diethylnaphthalen-1-amine;N,N-Diethyl-1-aminonaphthalene;1-(Diethylamino)naphthalene;1-Naphthylamine, N,N-diethyl-;N,N-Diethyl-.alpha.-naphthylamine;Diethyl-.alpha.-naphthylamine;diethyl-naphthalen-1-yl-amine;WI5L987JR2;N,N-Diethyl-alpha-naphthylamine;NSC 6340;NSC-6340;EINECS 201-576-8;NSC6340;1-Naphthylamine,N-diethyl-;N,N-diethyl-1-naphthylamin;N,N-Diethyl-1-naphtylamine;UNII-WI5L987JR2;1-Naphthalenamine,N-diethyl-;SCHEMBL517207;N,N-Diethyl-1-naphthalenamine;DTXSID7058915;N,N-Diethyl-1-naphthalenamine #;ADAL1020551;MFCD00046389;AKOS028108557;D0513;FT-0631390;T71388

Chemical Property of N,N-Diethyl-1-naphthylamine

Chemical Property:

• Vapor Pressure: 0.00288mmHg at 25°C
• Refractive Index: 1.5900-1.5940
• Boiling Point: 285°Cat760mmHg
• PKA: 6.69±0.20(Predicted)
• Flash Point: 121.1°C
• PSA: 3.24000
• Density: 1.024g/cm³
• LogP: 3.68600
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 199.136099547
• Heavy Atom Count: 15
• Complexity: 186

Purity/Quality:

98%min ^*data from raw suppliers

N,N-Diethyl-1-naphthylamine >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)C1=CC=CC2=CC=CC=C21

Technology Process of N,N-Diethyl-1-naphthylamine

There total 20 articles about N,N-Diethyl-1-naphthylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

naphthalene (91-20-3,71998-51-1,72931-45-4) + O-(2,4-dinitrophenyl)-N,N-diethylhydroxylamine (29746-98-3) → N,N-diethyl-1-naphthylamine (84-95-7)

Guidance literature:

With perchloric acid; tris(2,2'-bipyridyl)ruthenium dichloride; In water; acetonitrile; at 20 ℃; Sealed tube; Inert atmosphere; Irradiation;

DOI:10.1002/anie.201708693

Reference yield: 72.0%

1-Iodonaphthalene (90-14-2) + diethylamine (109-89-7) → N,N-diethyl-1-naphthylamine (84-95-7)

Guidance literature:

With potassium phosphate; copper(l) iodide; CVT-2537; In dimethyl sulfoxide; at 90 ℃; for 40h; Inert atmosphere;

DOI:10.1021/ol301135c

Reference yield:

1-amino-naphthalene (134-32-7) + ethyl iodide (75-03-6) → N,N-diethyl-1-naphthylamine (84-95-7) + 1-N-ethylnaphthylamine (118-44-5)

Guidance literature:

In N,N-dimethyl-formamide; at 200 ℃; for 0.0666667h; under 5250.53 Torr; Flow reactor; Green chemistry;

DOI:10.1055/s-0034-1379895

upstream raw materials:

diethyl ether

1-Fluoronaphthalene

lithium diethylamide

ethanol

Downstream raw materials:

diethyl-[1]naphthyl-amine; compound with 1,3,5-trinitro-benzene

{4-[Bis-(4-dimethylamino-phenyl)-methyl]-naphthalen-1-yl}-diethyl-amine

1-N-ethylnaphthylamine

1-amino-naphthalene

Refernces

• 1、 Kong, Nam Sik,Jung, Hyocheol,Kim, Beomjin,Lee, Chan Kyu,Kong, Hoyoul,Jun, Kun,Kim, Jin Chul,Noh, Seung Man,Cheong, In Woo,Park, Jongwook,Park, Young IL. "Development of dimeric triarylmethine derivatives with improved thermal and photo stability for color filters". . p. 242 - 248. Retrieved 2017.
• 2、 -. "Dimer-type triarylmethane dye compounds, blue resin composition comprising the same for color filter and color filter using the same". Paragraph 0070-0074. . Retrieved 2018/05/03.
• 3、 Choi, Yong-Sung,Kim, Yoon-Jung,Shen, Liu-Lan,Lee, Yong Sup,Jeong, Jin-Hyun. "Direct N-alkylation of aromatic amines using a microflow reactor: Enhancement of selectivity and reactivity". supporting information. p. 970 - 974. Retrieved 2015/04/27.