ACRYLICACID,3-HYDROXYPROPYLESTER

Base Information

• Chemical Name: ACRYLICACID,3-HYDROXYPROPYLESTER
• CAS No.: 2761-08-2
• Molecular Formula: C6H10 O3
• Molecular Weight: 130.144
• Hs Code.: 2916129000
• Mol file: 2761-08-2.mol

Synonyms:Acrylicacid, 3-hydroxypropyl ester (7CI,8CI); 1,3-Propanediol monoacrylate;3-Hydroxypropyl acrylate; Rocryl 430; g-Hydroxypropyl acrylate

Chemical Property of ACRYLICACID,3-HYDROXYPROPYLESTER

Chemical Property:

• Boiling Point: 224.5±23.0 °C(Predicted)
• PKA: 14.67±0.10(Predicted)
• PSA: 46.53000
• Density: 1.052±0.06 g/cm3(Predicted)
• LogP: 0.09800

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ACRYLICACID,3-HYDROXYPROPYLESTER

There total 5 articles about ACRYLICACID,3-HYDROXYPROPYLESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + trimethyleneglycol (504-63-2) → 2-propenoic acid 1,3-propanediyl ester (24493-53-6) + 3-hydroxypropyl acrylate (2761-08-2)

Guidance literature:

With Novozyme 435; In 2-methyl-2-butanol; at 50 ℃; for 24h; Enzymatic reaction;

DOI:10.1002/pola.24041

Reference yield:

acrylic acid (79-10-7) + methyloxirane (75-56-9,16033-71-9) → 3-hydroxypropyl acrylate (2761-08-2)

Guidance literature:

acrylic acid; With cupric dibutyldithiocarbamate; chromium(lll) acetate; 4-methoxy-phenol; at 65 ℃;

methyloxirane; at 60 - 65 ℃; for 9h; Product distribution / selectivity;

Reference yield:

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + trimethyleneglycol (504-63-2) → 3-hydroxypropyl acrylate (2761-08-2)

Guidance literature:

With Novozyme 435; In tert-Amyl alcohol; at 50 ℃; for 120h; Inert atmosphere; Molecular sieve; Enzymatic reaction;

DOI:10.1016/j.molcatb.2009.09.008

upstream raw materials:

3-hydroxypropyl 3-hydroxypropanoate

acrylic acid

methyloxirane

acrylic acid methyl ester

Downstream raw materials:

2-(Hydroxy-phenyl-methyl)-acrylic acid 3-hydroxy-propyl ester

2-(Hydroxy-p-tolyl-methyl)-acrylic acid 3-hydroxy-propyl ester

Refernces

• 1、 Popescu, Dragos,Hoogenboom, Richard,Keul, Helmut,Moeller, Martin. "Hydroxy functional acrylate and methacrylate monomers prepared via lipase-catalyzed transacylation reactions". experimental part. p. 80 - 89. Retrieved 2010/08/20.
• 2、 -. "Process for the production of hydroxyalkyl (meth)acrylates". Page/Page column 3. . Retrieved 2009/09/05.