Tetramethylhydrazine

Base Information

• Chemical Name: Tetramethylhydrazine
• CAS No.: 6415-12-9
• Molecular Formula: C4H12 N2
• Molecular Weight: 88.1527
• Hs Code.: 2928000090
• European Community (EC) Number: 229-119-8
• UNII: CHW03U0AA6
• DSSTox Substance ID: DTXSID10214358
• Nikkaji Number: J207.027H
• Wikidata: Q27275468
• Mol file: 6415-12-9.mol

Synonyms:tetramethylhydrazine;tetramethylhydrazine ion;tetramethylhydrazine monohydrochloride

Chemical Property of Tetramethylhydrazine

Chemical Property:

• Vapor Pressure: 148mmHg at 25°C
• Refractive Index: n20/D 1.404
• Boiling Point: 67.1°C at 760 mmHg
• Flash Point: 27 °C
• PSA: 6.48000
• Density: 0.777 g/mL at 20 °C(lit.)
• LogP: 0.02460
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 88.100048391
• Heavy Atom Count: 6
• Complexity: 26.5

Purity/Quality:

98%Min ^*data from raw suppliers

Tetramethylhydrazine ^*data from reagent suppliers

Safty Information:

• Statements: 10
• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CN(C)N(C)C

Technology Process of Tetramethylhydrazine

There total 27 articles about Tetramethylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dimethylamino radical (15337-44-7) → tetramethylhydrazine (6415-12-9) + N-methylmethanimine (1761-67-7) + dimethyl amine (124-40-3)

Guidance literature:

In gaseous matrix; at 29.9 ℃; under 0.004 Torr; Rate constant; Mechanism; in He matrix; determination of the disproportionation to recombination ratio;

DOI:10.1021/j100138a012

Reference yield:

dimethylchloroamine (1585-74-6) + urea (57-13-6) → tetramethylhydrazine (6415-12-9) + dimethyl amine (124-40-3) + N,N-Dimethylhydrazine (57-14-7)

Guidance literature:

With potassium hydroxide; In methanol; tert-butyl alcohol; for 8.25h; Ambient temperature;

Reference yield:

N,N-Dimethylhydrazine (57-14-7) + acetone (67-64-1) → 1,3-dimethyl-1H-pyrazole (694-48-4) + tetramethylhydrazine (6415-12-9) + Acetone dimethylhydrazone (13483-31-3) + N-Nitrosodimethylamine (62-75-9) + acetaldehydedimethylhydrazone (7422-90-4) + 1,2-bis(2-methyl-2-phenylhydrazone) (26757-28-8) + propan-2-one azine (627-70-3)

Guidance literature:

With shungite;

DOI:10.1134/S1070363214060097

upstream raw materials:

N,N'-diformyl-N,N'-dimethyl-hydrazine

N,N-Dimethyltrimethylsilylamine

dimethyl-piperidin-1-yl-amine

tetramethylhydrazine cation radical

Downstream raw materials:

dimethylamine borane

Dimethyl-piperidin-1-yl-amine

Dimethyl-pyrrolidin-1-yl-amine

tetramethylhydrazine cation radical

Refernces

• 1、 Zenkevich,Ul'Yanov,Golub,Buryak. "Chromatographic component of identification of the transformation products of 1,1-dimethylhydrazine in the presence of sulfur". . p. 1106 - 1114. Retrieved 2014/08/05.
• 2、 Lazarou, Yannis G.,Kambanis, Kyriakos G.,Papagiannakopoulos, Panos. "Gas-Phase Reactions of (CH3)2N Radicals with NO and NO2". . p. 2110 - 2115. Retrieved 2007/10/02.