N,N-dimethylpiperidin-1-amine

Base Information

• Chemical Name: N,N-dimethylpiperidin-1-amine
• CAS No.: 49840-60-0
• Molecular Formula: C7H16 N2
• Molecular Weight: 128.217
• Mol file: 49840-60-0.mol

Synonyms:N-(Dimethylamino)piperidine

Chemical Property of N,N-dimethylpiperidin-1-amine

Chemical Property:

• Vapor Pressure: 1.82mmHg at 25°C
• Boiling Point: 166.1°C at 760 mmHg
• PKA: 10.04±0.20(Predicted)
• Flash Point: 47.9°C
• PSA: 6.48000
• Density: 0.92g/cm³
• LogP: 0.88680

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N-dimethylpiperidin-1-amine

There total 14 articles about N,N-dimethylpiperidin-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

(2,6-Bis-benzotriazol-1-yl-piperidin-1-yl)-dimethyl-amine (126216-65-7) → dimethyl-piperidin-1-yl-amine (49840-60-0)

Guidance literature:

With sodium tetrahydroborate; In tetrahydrofuran; Ambient temperature;

DOI:10.1021/jo00297a041

Reference yield:

dimethyl-piperidin-1-yl-amine (49840-60-0) + tetramethylhydrazine cation radical (6415-12-9,14213-69-5) → tetramethylhydrazine (6415-12-9) + Dimethyl-piperidin-1-yl-amine (49840-60-0)

Guidance literature:

In chloroform; benzene; at 276.9 ℃; Rate constant; Thermodynamic data; ΔG(excit); insitu ionization;

DOI:10.1021/ja00239a015

Reference yield:

1,2-dimethylpyrazolidine (38704-89-1) + Dimethyl-piperidin-1-yl-amine (49840-60-0) → dimethyl-piperidin-1-yl-amine (49840-60-0) + 1,2-dimethylpyrazolidine cation radical (38704-89-1)

Guidance literature:

In chloroform; benzene; at 276.9 ℃; Rate constant; Thermodynamic data; ΔG(excit); insitu ionization;

DOI:10.1021/ja00239a015

upstream raw materials:

octahydro-[1,1']bipyrrolyl

1-(piperidin-1-yl)piperidine

dimethylaminopyrrolidine

N,N'-Bis-(2,2-dimethyl-propyl)-N,N'-dimethyl-hydrazine

Downstream raw materials:

N,N'-Dipiperidin-Kation-Radikal

[1,1']Bipiperidinyl

tetramethylhydrazine

Dimethyl-pyrrolidin-1-yl-amine

Refernces

• 1、 Nelsen, Stephen F.,Rumack, Daniel T.,Meot-Ner (Mautner), Michael. "Kinetic Effects of an Unusually Large Neutral to Radical Cation Geometry Change. Slow Electron-Transfer Reactions between Alkylhydrazines". . p. 1373 - 1379. Retrieved 2007/10/02.