Chloryl fluoride

Base Information

• Chemical Name: Chloryl fluoride
• CAS No.: 13637-83-7
• Molecular Formula: ClF O2
• Molecular Weight: 86.4502
• DSSTox Substance ID: DTXSID00159769
• Nikkaji Number: J96.025J
• Wikipedia: Chloryl fluoride,Chloryl_fluoride
• Wikidata: Q1916758
• Mol file: 13637-83-7.mol

Synonyms:Chloryl fluoride;13637-83-7;ClO2F;DTXSID00159769;Q1916758

Chemical Property of Chloryl fluoride

Chemical Property:

• Melting Point: -115℃ [CRC10]
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 34.14000
• Density: g/cm³
• LogP: 0.87210
• Water Solubility.: reac H2O [CRC10]Density, g/L: 3.534 [CRC10]
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 85.9570851
• Heavy Atom Count: 4
• Complexity: 48.9

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O=Cl(=O)F

Technology Process of Chloryl fluoride

There total 35 articles about Chloryl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorine pentafluoride (184851-42-1,478167-78-1,13637-63-3,676353-68-7,478167-76-9) + potassium nitrate → FClO2 (13637-83-7) + nitrylfluoride (10022-50-1)

Guidance literature:

In neat (no solvent); byproducts: KF, KClF4; stainless-steel cylinder loaded with KNO3, ClF5 (excess) added at -196°C, cylinder warmed from -196°C to room temp., kept for 28d with frequent agitation, cooled back to -196°C; fractional condensation;

Reference yield:

caesium nitrate + chlorine pentafluoride (184851-42-1,478167-78-1,13637-63-3,676353-68-7,478167-76-9) → FClO2 (13637-83-7) + nitrylfluoride (10022-50-1)

Guidance literature:

In neat (no solvent); byproducts: CsF, CsClF4, F2; stainless-steel cylinder loaded with CsNO3, ClF5 (excess) added at -196°C, cylinder warmed from -196°C to room temp., kept for 32d with frequent agitation, cooled back to -196°C; fractional condensation;

Reference yield:

chlorine pentafluoride (184851-42-1,478167-78-1,13637-63-3,676353-68-7,478167-76-9) + lithium nitrate → FClO2 (13637-83-7) + nitrylfluoride (10022-50-1)

Guidance literature:

In neat (no solvent); byproducts: LiF; stainless-steel cylinder loaded with LiNO3, ClF5 (excess) added at -196°C, cylinder warmed from -196°C to room temp., kept for 3d with frequent agitation, cooled back to -196°C; fractional condensation;

upstream raw materials:

chlorine dioxide

hydrogen fluoride

chlorine monofluoride

chlorine pentafluoride

Downstream raw materials:

iodine

sulfur trioxide

chlorine dioxide

chlorine

Refernces

• 1、 Bougon,Huy, T. Bui,Charpin. "Acid properties of the oxytetrafluorides of molybdenum, tungsten, and uranium toward some inorganic fluoride ion donors". . p. 1822 - 1830. Retrieved 1975.
• 2、 Shrewsberry, R. C.,Williamson, E. L.. "". . p. 2535 - 2539. Retrieved 1966.
• 3、 Christe, Karl O.,Wilson, Richard D.,Schack, Carl J.. "Syntheses and properties of FOIF4O, ClOIF4O, HOIF4O, and tetrafluoroperiodates". . p. 2104 - 2114. Retrieved 2008/10/08.