Methyl chloroacetate

Base Information Edit

Chemical Name:Methyl chloroacetate
CAS No.:96-34-4
Molecular Formula:C3H5ClO2
Molecular Weight:108.525
Hs Code.:2915400090
European Community (EC) Number:202-501-1
ICSC Number:1410
NSC Number:2635
UN Number:2295
UNII:450VSB182I
DSSTox Substance ID:DTXSID9041576
Nikkaji Number:J3.968C
Wikidata:Q188382
Mol file:96-34-4.mol

Synonyms:METHYL CHLOROACETATE;96-34-4;methyl 2-chloroacetate;Chloroacetic acid methyl ester;Methyl monochloroacetate;Acetic acid, chloro-, methyl ester;Methyl chloroethanoate;Methyl monochloracetate;Methyl alpha-chloroacetate;Monochloroacetic acid methyl ester;NSC 2635;UN2295;CCRIS 7749;Methylester kyseliny chloroctove;ClH2CCOOCH3;HSDB 5303;EINECS 202-501-1;Acetic acid, 2-chloro-, methyl ester;Methylester kyseliny chloroctove [Czech];UNII-450VSB182I;AI3-39185;chloro-acetic acid methyl ester;2-Chloroacetic acid methyl ester;450VSB182I;Monochloroacetic acid, methyl ester;NSC-2635;MFCD00000931;EC 202-501-1;Methylchloracetat;methyl chloracetate;methyl chloroactate;methyl chioroacetate;methyl chloro-acetate;Methyl monochloroacete;methyl-2-chloroacetate;Chloroacetic acid methyl;MED (CHRIS Code);methyl 2-chloro-acetate;chloroacetic methyl ester;Methyl chloroacetate, 99%;chloroacetic acid methylester;Chloroacetic acid-methyl ester;SCHEMBL140582;chloroacetic acid, methyl ester;DTXSID9041576;METHYL CHLOROACETATE [MI];Methyl ester of Chloroacetic acid;NSC2635;2-chloro-acetic acid methyl ester;BCP30634;METHYL .ALPHA.-CHLOROACETATE;NA2295;STL197883;AKOS000119621;UN 2295;UN-2295;Methyl chloroacetate [UN2295] [Poison];Methyl chloroacetate [UN2295] [Poison];FT-0623623;EN300-19700;Q188382;F8889-8024;Methyl chloroacetate, PESTANAL(R), analytical standard;Chloroacetic acid methyl ester 1000 microg/mL in Methyl-tert-butyl ether;Methyl chloroacetate, certified reference material, 1000 mug/mL in methyl tert-butyl ether;2-Chloroacetic Acid Methyl Ester;Methyl Monochloroacetate;Methyl (c) paragraph sign-Chloroacetate;Methyl 2-Chloroacetate

Suppliers and Price of Methyl chloroacetate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 113 raw suppliers

Chemical Property of Methyl chloroacetate Edit

Chemical Property:

Appearance/Colour:clear colourless liquid
Vapor Pressure:8.97mmHg at 25°C
Melting Point:-33 °C
Refractive Index:1.421 - 1.423
Boiling Point:132.2 °C at 760 mmHg
Flash Point:51.7 °C
PSA：26.30000
Density:1.167 g/cm³
LogP:0.39820
Water Solubility.:28 g/L (20℃)
XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:107.9978071
Heavy Atom Count:6
Complexity:52.8
Transport DOT Label:Poison Flammable Liquid

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s): T,Xi,F
Hazard Codes: T:Toxic;
Statements: R10:; R23/25:; R37/38:; R41:;
Safety Statements: S26:; S37/39:; S45:;

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Chemical Classes:Other Classes -> Chloroacetic Acid Derivatives
Canonical SMILES:COC(=O)CCl
Inhalation Risk:A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20 °C.
Effects of Short Term Exposure:The substance is corrosive to the skin. The substance is severely irritating to the eyes. The substance is irritating to the respiratory tract.

Technology Process of Methyl chloroacetate

There total 48 articles about Methyl chloroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 6832-16-2
methyl diazoacetate

: 96-34-4
methyl chloroacetate

Guidance literature:: With titanium tetrachloride; acrylic acid methyl ester; In dichloromethane; at 20 ℃; for 0.0333333h; Inert atmosphere;
DOI:10.1007/s11172-010-0194-0

Reference yield: 94.0%

: 67-56-1
methanol

: 79-11-8
chloroacetic acid

: 96-34-4
methyl chloroacetate

Guidance literature:: F-4SK (H form); In dichloromethane; at 41 ℃; for 15h;

Reference yield: 90.0%

: 6832-16-2
methyl diazoacetate

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 19255-80-2
5-methoxycarbonyl-pyrazoline-3-carboxylic acid methyl ester

: 96-34-4
methyl chloroacetate

Guidance literature:: With ethylaluminum dichloride; In hexane; dichloromethane; at 20 ℃; for 0.0666667h; Inert atmosphere;
DOI:10.1007/s11172-010-0194-0