3-Methoxycyclohexene

Base Information

• Chemical Name: 3-Methoxycyclohexene
• CAS No.: 2699-13-0
• Molecular Formula: C7H12 O
• Molecular Weight: 112.172
• Hs Code.: 2909200090
• Mol file: 2699-13-0.mol

Synonyms:Ether,2-cyclohexen-1-yl methyl (6CI,7CI,8CI); 1-Methoxy-2-cyclohexene; 2-Cyclohexenylmethyl ether; 3-Methoxy-1-cyclohexene; 3-Methoxycyclohexene; NSC 155565

Chemical Property of 3-Methoxycyclohexene

Chemical Property:

• Vapor Pressure: 8.78mmHg at 25°C
• Refractive Index: 1.4530-1.4570
• Boiling Point: 137.3°Cat760mmHg
• Flash Point: 26.9°C
• PSA: 9.23000
• Density: 0.89g/cm³
• LogP: 1.74150

Purity/Quality:

98%,99%, ^*data from raw suppliers

3-Methoxycyclohexene >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Methoxycyclohexene

There total 41 articles about 3-Methoxycyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bromo-1 methoxy-2 cyclohexane (24618-31-3) → 3-methoxycyclohexene (2699-13-0)

Guidance literature:

With 18-crown-6 ether; potassium tert-butylate; In benzene; Heating;

DOI:10.1016/S0040-4039(00)99928-3

Reference yield: 94.0%

Cyclohex-2-enol (822-67-3) + methyl iodide (74-88-4) → 3-methoxycyclohexene (2699-13-0)

Guidance literature:

With sodium hydride; In tetrahydrofuran; paraffin; for 24h; Ambient temperature;

DOI:10.1016/S0022-1139(00)81950-8

Reference yield: 93.0%

2-chloro-3-methoxycyclohexene (474834-44-1) → 3-methoxycyclohexene (2699-13-0)

Guidance literature:

2-chloro-3-methoxycyclohexene; With naphthalene; lithium; In tetrahydrofuran; at -78 ℃; for 3h;

With water; In tetrahydrofuran; at -78 ℃; for 1h;

DOI:10.1016/S0040-4020(02)00454-4

upstream raw materials:

3-chloro-cyclohexene

sodium methylate

trans-1,2-dibromocyclohexane

methanol

Downstream raw materials:

(1α,2β,3α)-1,2,3-cyclohexanetriol

rac-cyclohexane-1,2,3-triol

2(e)-bromo-1(a),3(e)-dimethoxycyclohexane

r-1-iodo-c-2-methoxy-t-6-thiocyanatocyclohexane

Refernces

• 1、 Da Silva,Berlini. "Exploring the reaction pathways of Pd(II)-catalyzed cyclohexene oxidation with molecular oxygen: Vinylic and allylic oxidation, disproportionation and oxidative dehydrogenation". . p. 7996 - 8005. Retrieved 2016/09/12.
• 2、 Yusubov,Zholobova,Filimonova,Chi, Ki-Whan. "New oxidative transformations of alkenes and alkynes under the action of diacetoxyiodobenzene". . p. 1735 - 1742. Retrieved 2007/10/03.