(p-Methoxyphenyl)triphenylmethane

Base Information

• Chemical Name: (p-Methoxyphenyl)triphenylmethane
• CAS No.: 7402-89-3
• Molecular Formula: C26H22O
• Molecular Weight: 350.46
• Mol file: 7402-89-3.mol

Synonyms:4-Methoxy-1-triphenylmethyl-benzol;Methyl-(4-trityl-phenyl)-aether;Methyl-(4-triphenylmethyl-phenyl)-aether;4-trityl-anisole;Triphenyl-(4-methoxy-phenyl)-methan;4-Trityl-anisol;(p-Methoxyphenyl)triphenylmethane;1-methoxy-4-tritylbenzene;

Chemical Property of (p-Methoxyphenyl)triphenylmethane

Chemical Property:

• Vapor Pressure: 1.85E-08mmHg at 25°C
• Boiling Point: 467.3°C at 760 mmHg
• Flash Point: 192.2°C
• PSA: 9.23000
• Density: 1.095g/cm³
• LogP: 6.07790

Purity/Quality:

99% ^*data from raw suppliers

1-METHOXY-4-TRITYLBENZENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (p-Methoxyphenyl)triphenylmethane

There total 21 articles about (p-Methoxyphenyl)triphenylmethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

triphenylmethyl alcohol (76-84-6) + methoxybenzene (100-66-3) → (4-methoxyphenyl)triphenylmethane (7402-89-3)

Guidance literature:

With silica gel supported sodium hydrogen sulfate; In 1,2-dichloro-ethane; at 80 ℃; for 16h;

DOI:10.1016/j.tet.2012.06.063

Reference yield: 74.0%

triphenylmethane (519-73-3) + methoxybenzene (100-66-3) → (4-methoxyphenyl)triphenylmethane (7402-89-3) + 9-(4-methoxyphenyl)-9-phenylfluorene (78229-08-0)

Guidance literature:

With trifluorormethanesulfonic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,2-dichloro-ethane; at 100 ℃; for 6h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1055/s-0036-1588563

Reference yield: 51.0%

9-(p-methoxyphenyl)-9-phenylthioxanthene (41959-24-4) → (4-methoxyphenyl)triphenylmethane (7402-89-3)

Guidance literature:

With Raney nickel; In tetrahydrofuran; at 75 ℃; Inert atmosphere;

DOI:10.1016/j.tetlet.2018.09.056

upstream raw materials:

diazomethane

4-tritylphenol

trityl chloride

methoxybenzene

Downstream raw materials:

4-tritylphenol

biphenyl

benzhydryl methyl ether

4-methoxylbiphenyl

Refernces

• 1、 Griffin, Paul J.,Fava, Matthew A.,Whittaker, St. John T.,Kolonko, Kristopher J.,Catino, Arthur J.. "Synthesis of tetraarylmethanes via a Friedel-Crafts cyclization/desulfurization strategy". . p. 3999 - 4002. Retrieved 2018/10/02.
• 2、 Sato, Yuta,Aoyama, Tadashi,Takido, Toshio,Kodomari, Mitsuo. "Direct alkylation of aromatics using alcohols in the presence of NaHSO 4/SiO2". supporting information; experimental part. p. 7077 - 7081. Retrieved 2012/08/28.