1,2,4-Trioxolane

Base Information

• Chemical Name: 1,2,4-Trioxolane
• CAS No.: 289-14-5
• Molecular Formula: C2H4 O3
• Molecular Weight: 76.052
• Mol file: 289-14-5.mol

Synonyms:1,2,4-Trioxacyclopentane;Ethene secondary ozonide; Ethene, ozonide; Ethylene ozonide

Chemical Property of 1,2,4-Trioxolane

Chemical Property:

• Vapor Pressure: 371mmHg at 25°C
• Refractive Index: 1.3840 (estimate)
• Boiling Point: 44.8°Cat760mmHg
• Flash Point: °C
• PSA: 27.69000
• Density: 1.229g/cm³
• LogP: -0.12020

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2,4-Trioxolane

There total 15 articles about 1,2,4-Trioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

formic acid ethyl ester (109-94-4) → 1,2,4-trioxolane (289-14-5) + 3-Phenyl-1,2,4-trioxolane (23253-30-7) + benzaldehyde (100-52-7) + 3-ethoxy-1,2,4-trioxolane (90150-47-3)

Guidance literature:

With styrene; ozone; at -78 ℃; Yield given;

DOI:10.1021/ja00323a070

Reference yield:

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + Methyl formate (107-31-3) → 1,2,4-trioxolane (289-14-5) + 3-Phenyl-1,2,4-trioxolane (23253-30-7) + benzaldehyde (100-52-7) + 3-methoxy-1,2,4-trioxolane (90150-46-2)

Guidance literature:

With ozone; at -78 ℃; Product distribution; Mechanism; further esters;

DOI:10.1021/ja00323a070

Reference yield:

isobutene (115-11-7,15220-85-6) → 2-methyl-1,2-epoxypropane (558-30-5) + 1,2,4-trioxolane (289-14-5) + 3,3-dimethyl-1,2,4-trioxolane (22409-33-2) + dimethylketene (598-26-5) + 2-Methyl-1,2-propanediol (558-43-0) + 2-hydroxy-2-methylpropanal (20818-81-9)

Guidance literature:

With ozone; for 0.00388889h; under 4.1 Torr; Product distribution; Mechanism; reaction in gas phase; mass spectrum of ozone and title compound;

DOI:10.1021/ja00403a031

upstream raw materials:

styrene

Methyl formate

Trioxolane

propene

Downstream raw materials:

formaldehyd

formic acid

methane

carbon dioxide

Refernces

• 1、 Samuni,Fraenkel,Haas,Fajgar,Pola. "Environmental effects on the formation of the primary and secondary ozonides of ethylene at cryogenic temperatures". . p. 3687 - 3693. Retrieved 1996.
• 2、 Feltham, Emma J.,Almond, Matthew J.,Marston, George,Ly, Vivienne P.,Wiltshire, Karen S.. "Reactions of alkenes with ozone in the gas phase: A matrix-isolation study of secondary ozonides and carbonyl-containing reaction products". . p. 2605 - 2616. Retrieved 2007/10/03.