2,4,6-triphenyl-1,2,3,4-tetrahydro-1,2,4,5-tetrazine

Base Information

• Chemical Name: 2,4,6-triphenyl-1,2,3,4-tetrahydro-1,2,4,5-tetrazine
• CAS No.: 22459-57-0
• Molecular Formula: C20H18 N4
• Molecular Weight: 314.39
• Mol file: 22459-57-0.mol

Synonyms:s-Tetrazine,1,2,3,4-tetrahydro-2,4,6-triphenyl- (7CI,8CI)

Chemical Property of 2,4,6-triphenyl-1,2,3,4-tetrahydro-1,2,4,5-tetrazine

Chemical Property:

• Vapor Pressure: 3.31E-08mmHg at 25°C
• Boiling Point: 447.6°Cat760mmHg
• Flash Point: 224.5°C
• Density: 1.15g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4,6-triphenyl-1,2,3,4-tetrahydro-1,2,4,5-tetrazine

There total 40 articles about 2,4,6-triphenyl-1,2,3,4-tetrahydro-1,2,4,5-tetrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

1,3,5-triphenylverdazyl (2154-65-6) + Toluene-4-sulfonic acid adamantan-1-yl ester (16200-57-0) + acetonitrile (75-05-8,26809-02-9) → adamantane (281-23-2) + 1-adamanthanol (768-95-6) + N-(1-adamantyl)acetamide (880-52-4) + 2,4,6-triphenyl-1--1,2,3,4-tetrahydro-1,2,4,5-tetrazine (85963-93-5) + triphenylverdazylium p-toluenesulfonate (85963-94-6) + 2,4,6-triphenylverdazyl (22459-57-0)

Guidance literature:

With water; for 480h; Product distribution; Rate constant; Mechanism; Ambient temperature; var. solvents, var. reaction partners; other objects -kinetic and energy data of ionization;

Reference yield:

1-bromo-1-methylcyclohexane (931-77-1) + 1,3,5-triphenylverdazyl (2154-65-6) → 1-methylcyclohex-1-ene (591-49-1) + 2,4,6-triphenylverdazylium bromide (51940-11-5) + 2,4,6-triphenylverdazyl (22459-57-0)

Guidance literature:

In sulfolane; at 25 ℃; Further Variations:; Solvents; Temperatures; Kinetics; Thermodynamic data;

Reference yield:

1,3,5-triphenylverdazyl (2154-65-6) + thiophenol (108-98-5) → 2,4,6-triphenylverdazyl (22459-57-0) + diphenyldisulfane (882-33-7)

Guidance literature:

In acetonitrile; at 20 ℃; Thermodynamic data; Kinetics; Rate constant; oth. temperature, E(activ.), ΔS(activ.),;

upstream raw materials:

phenylacetic acid

1,3,5-triphenylverdazyl

2-phenyl-2-imidazoline

2,4,6-triphenylverdazylium bromide

Downstream raw materials:

2,4,6-triphenylverdazyl radical

2,4,6-triphenylverdazylium bromide

1,3,5-triphenylverdazyl

chloroacetic acid

Refernces

• 1、 Dvorko,Koshchii,Ponomareva. "Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXIV. Solvent Effect on the Heterolysis Rate of 1-Chloro-1-methylcyclohexane. Correlation Analysis of Solvation Effects in Heterolysis of 1-Chloro-1-methylcyclohexane and 1-Chloro-1-methylcyclopentane". . p. 204 - 212. Retrieved 2003.
• 2、 Ponomarev,Zaliznyi,Dvorko. "Kinetics and mechanism of monomolecular heterolysis of commercial organohalogen compounds: XLIII. Solvent effect on activation parameters of dehydrochlorination of 3-chloro-3-methylbut-1-ene. Correlation analysis of solvation effects". . p. 1204 - 1214. Retrieved 2008/02/12.