2,4,6-Triphenylverdazyl

Base Information

• Chemical Name: 2,4,6-Triphenylverdazyl
• CAS No.: 2154-65-6
• Molecular Formula: C20H17 N4
• Molecular Weight: 313.382
• European Community (EC) Number: 919-938-5
• Nikkaji Number: J669.157I
• Mol file: 2154-65-6.mol

Synonyms:2,4,6-triphenylverdazyl

Chemical Property of 2,4,6-Triphenylverdazyl

Chemical Property:

• Vapor Pressure: 3.31E-08mmHg at 25°C
• Boiling Point: 447.6°Cat760mmHg
• Flash Point: 224.5°C
• PSA: 35.45000
• Density: 1.15g/cm³
• LogP: 3.94570
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 313.145321559
• Heavy Atom Count: 24
• Complexity: 387

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1N(N=C([N]N1C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of 2,4,6-Triphenylverdazyl

There total 18 articles about 2,4,6-Triphenylverdazyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,4,6-triphenylverdazylium bromide (51940-11-5) → 1,3,5-triphenylverdazyl (2154-65-6)

Guidance literature:

With N,N-dimethyl-p-anisidine; In nitrobenzene; at 40 ℃;

DOI:10.1134/S1070363206050239

Reference yield: 55.2%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1,3,5-triphenylformazan (531-52-2) → 1,3,5-triphenylverdazyl (2154-65-6)

Guidance literature:

formaldehyd; 1,3,5-triphenylformazan; With potassium hydrogensulfate; In water; N,N-dimethyl-formamide; at 20 ℃; for 24h;

formaldehyd; With sodium hydroxide; In water; N,N-dimethyl-formamide; at 20 ℃; for 0.5h;

DOI:10.1134/S1070363220030044

Reference yield: 54.2%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1,3,5-triphenylformazan (49624-20-6) → 1,3,5-triphenylverdazyl (2154-65-6)

Guidance literature:

With sodium hydroxide; oxygen; In water; N,N-dimethyl-formamide; for 3h;

DOI:10.1021/ol702163a

upstream raw materials:

1-ethoxalyl-2,4,6-triphenyl-1,2,3,4-tetrahydro-sym-tetrazine

4-oxo-2,2,6,6-tetramethylpiperidin-oxyl

2,4,6-triphenylverdazyl

formaldehyd

Downstream raw materials:

2,4,6-triphenylverdazyl

1-Adamantan-1-yl-2,4,6-triphenyl-1,2,3,4-tetrahydro-[1,2,4,5]tetrazine

2,4,6-triphenyl-1--1,2,3,4-tetrahydro-1,2,4,5-tetrazine

triphenylverdazylium iodide

Refernces

• 1、 Serebryakov,Kryzhanovskaya,Dzhurinskaya,Kladova,Azarova. "Is triphenylverdazyl an indicator for solvent-separated ion pair?". . p. 1331 - 1335. Retrieved 2005.
• 2、 Burtasov, A. A.,Chernyaeva, O. Yu.,Kostryukov, S. G.,Kozlov, A. Sh.,Pryanichnikova, M. K.,Tanaseichuk, B. S.. "Triarylverdazyl radicals as promising redox-active components of rechargeable organic batteries". . p. 1321 - 1328. Retrieved 2020/09/07.