VINYLCYCLOPROPANE

Base Information

• Chemical Name: VINYLCYCLOPROPANE
• CAS No.: 693-86-7
• Molecular Formula: C5H8
• Molecular Weight: 68.1185
• Hs Code.: 2902199090
• Mol file: 693-86-7.mol

Synonyms:Cyclopropane,ethenyl-;cyclopropyl-;

Chemical Property of VINYLCYCLOPROPANE

Chemical Property:

• Vapor Pressure: 589mmHg at 25°C
• Melting Point: -109.81 °C
• Refractive Index: 1.578
• Boiling Point: 32.114 °C at 760 mmHg
• PSA: 0.00000
• Density: 0.919 g/cm³
• LogP: 1.58240
• Storage Temp.: Amber Vial, Refrigerator, Under inert atmosphere
• Solubility.: Chloroform (Sparingly)

Purity/Quality:

99% ^*data from raw suppliers

Vinylcyclopropane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Vinylcyclopropane is a useful synthetic intermediate. Vinylcyclopropane and its derivatives can participate in a variety of transition-metal-catalyzed multicomponent cycloadditions to produce five- to eight-membered carbocycles.

Technology Process of VINYLCYCLOPROPANE

There total 7 articles about VINYLCYCLOPROPANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

1,4-Pentadiene (591-93-5) → 1-methylbuta-1,3-diene (2004-70-8,17410-45-6,25212-15-1,64940-84-7) + ethenylcyclopropane (693-86-7) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) + cyclopentene (142-29-0)

Guidance literature:

Product distribution; Mechanism; Plasmolysis (40 W, 3.48mmol/min, 13.56 MHz);

DOI:10.1016/S0040-4039(00)85657-9

Reference yield:

cyclopentene (142-29-0) → cyclopent-1->3-enyl (10577-65-8) + bicyclo[2.1.0]pentane (185-94-4) + ethenylcyclopropane (693-86-7) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8)

Guidance literature:

at 526.9 ℃; Rate constant; pyrolysis, other temperature;

DOI:10.1021/j100238a019

Reference yield:

1,4-Pentadiene (591-93-5) → ethenylcyclopropane (693-86-7) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) + cyclopentene (142-29-0)

Guidance literature:

Title compound not separated from byproducts; Irradiation;

DOI:10.1021/jo00203a006

upstream raw materials:

2-ethoxy-ethanol

(±)-(1-chloroethyl)cyclopropane

1,4-Pentadiene

cyclopentene

Downstream raw materials:

(2-cyclopropylethene-1,1-diyl)dibenzene

Dichloressigsaeure-trichlorvinylester

2,2-dichloro-3-cyclopropylcyclobutanone

pentane

Refernces

• 1、 Mizobuchi, Yoshikazu,Miller, Larry L.. "RF Plasma Promoted Di- Π-methane Rearrangement of 3-Phenylpropene". . p. 318 - 321. Retrieved 2007/10/02.
• 2、 Tokuda, Masao,Suginome, Hiroshi,Miller, L.L.. "CYCLIZATION OF 1,4-DIENES IN AN RF PLASMA, AN APPARENT Di-Π-METHANE REARRANGEMENT". . p. 4573 - 4576. Retrieved 2007/10/02.