1-benzyl-2-phenyl-benzene

Base Information

• Chemical Name: 1-benzyl-2-phenyl-benzene
• CAS No.: 606-97-3
• Molecular Formula: C19H16
• Molecular Weight: 244.336
• Hs Code.: 2902909090
• Mol file: 606-97-3.mol

Synonyms:Biphenyl,2-benzyl- (6CI,7CI,8CI); 1-Benzyl-2-phenylbenzene; 2-Benzyl-1,1'-biphenyl;2-Benzylbiphenyl; 2-Benzyldiphenyl; NSC 231615; o-Benzylbiphenyl

Chemical Property of 1-benzyl-2-phenyl-benzene

Chemical Property:

• Melting Point: 55°C
• Refractive Index: 1.4750 (estimate)
• Boiling Point: 322.25°C (rough estimate)
• PSA: 0.00000
• Density: 1.0925 (estimate)
• LogP: 4.94440

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-benzyl-2-phenyl-benzene

There total 42 articles about 1-benzyl-2-phenyl-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2-phenylbenzyl bromide (19853-09-9) + phenyltriisopropoxytitanium(IV) (16635-23-7) → 2-benzyl-1,1'-biphenyl (606-97-3)

Guidance literature:

With palladium diacetate; Tri(p-tolyl)phosphine; In toluene; at 25 ℃; for 2h; Inert atmosphere;

DOI:10.1002/adsc.201000311

Reference yield: 98.0%

benzyl diethyl phosphate (884-90-2) + 2-Biphenylboronic acid (4688-76-0) → 2-benzyl-1,1'-biphenyl (606-97-3)

Guidance literature:

With palladium diacetate; potassium phosphate; triphenylphosphine; In toluene; at 90 ℃; for 16h;

DOI:10.1021/ol0517271

Reference yield: 92.0%

2-bromobenzylchloride (578-51-8) + phenylboronic acid (98-80-6) → 2-benzyl-1,1'-biphenyl (606-97-3)

Guidance literature:

With [Pd(3-[(2,6-diisopropylphenyl)-1-imidazolio]-2-quinoxalinide)(PPh₃)Cl₂]; potassium carbonate; In water; at 100 ℃; for 3h;

DOI:10.1002/ejoc.201701241

upstream raw materials:

biphenyl

benzyl chloride

anthranilic acid

toluene

Downstream raw materials:

2-Cyclohexylmethyl-bicyclohexyl

Refernces

• 1、 Freure, Garrett P. R.,Lavertu, Jean-Danick E.,Newman, Stephen G.,Skrotzki, Eric A.. "Palladium-Catalyzed Cross-Coupling of Superbase-Generated C(sp3) Nucleophiles". . p. 12258 - 12263. Retrieved 2021/10/26.
• 2、 Sengupta, Debasish,Pandey, Madhusudan K.,Mondal, Dipanjan,Radhakrishna, Latchupatula,Balakrishna, Maravanji S.. "Immobilization of an Aminobisphosphine–PdII Complex over Graphene Oxide: An Efficient and Reusable Catalyst for Suzuki–Miyaura, Ullmann Coupling and Cyanation Reactions". . p. 3374 - 3383. Retrieved 2018/05/08.