Mercurous chloride

Base Information

• Chemical Name: Mercurous chloride
• CAS No.: 104923-33-3
• Molecular Formula: 2Cl*Hg₂
• Molecular Weight: 472.086
• Mol file: 104923-33-3.mol

Synonyms:C.I. 77764; Mercurous chloride; Calomel; HgCl; Mercury chloride; Mercury (I) Chloride; Mercury monochloride; Mercury Protochloride

Chemical Property of Mercurous chloride

Chemical Property:

• Vapor Pressure: 33900mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mercurous chloride

There total 62 articles about Mercurous chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tetrachloromethane (56-23-5) + di-n-propylmercury (628-85-3) → mercury(I) chloride (104923-33-3) + 1-Chloropropane (540-54-5) + chloroform (67-66-3,8013-54-5) + n-propylmercury(II) chloride (2440-40-6) + mercury

Guidance literature:

In neat (no solvent); 150°C, 60 h; further products;

Reference yield: 89.0%

tetrachloromethane (56-23-5) + dibutylmercury (629-35-6) → mercury(I) chloride (104923-33-3) + n-Butyl chloride (109-69-3) + chloroform (67-66-3,8013-54-5) + n-butylmercuric chloride (543-63-5) + mercury

Guidance literature:

In neat (no solvent); 150°C, 25 h; further products;

Reference yield: 40.0%

tetrachloromethane (56-23-5) + oxygen (80937-33-3) + di-n-propylmercury (628-85-3) → mercury(I) chloride (104923-33-3) + 1-Chloropropane (540-54-5) + chloroform (67-66-3,8013-54-5) + n-propylmercury(II) chloride (2440-40-6) + mercury

Guidance literature:

In neat (no solvent); 100°C, 60 h; further products;

upstream raw materials:

aluminium

hydrogenchloride

oxygen

tris(pentafluorophenyl)(tetrahydrofuran)vanadium

Downstream raw materials:

mercury(II) selenide

dibutylmercury

HgCl₂(dpmp)

Refernces

• 1、 Haas, P.. "". . p. 325. Retrieved 1951.
• 2、 Wetton, E. A. M.,Higginson, W. C. E.. "". . . Retrieved 1965.
• 3、 Linhart, G. A.,Adams, E. Q.. "". . p. 948 - 950. Retrieved 1917.
• 4、 Launer, H. F.. "". . p. 865 - 874. Retrieved 1933.
• 5、 Findley, A.,Davies, M. J. P.. "". . p. 1550 - 1554. Retrieved 1913.
• 6、 Dhar. "". . . Retrieved 1919.
• 7、 Mukherjee, J.,Kumar, K. K.. "". . p. 2179 - 2184. Retrieved 1930.
• 8、 Weil, Matthias,Breitinger, Dietrich K.,Liehr, Guenther,Zuerbig, Juergen. "Structural investigations and thermal behaviour of mercury(II) sulfito complexes". . p. 429 - 434. Retrieved 2007.
• 9、 Lipscomb, G. F.,Hulett, G. A.. "". . p. 20 - 27. Retrieved 1916.
• 10、 Furman, N. F.,Murray, W. M.. "". . p. 429 - 433. Retrieved 1936.