tris(pentafluorophenyl)(tetrahydrofuran)vanadium

Base Information

• Chemical Name: tris(pentafluorophenyl)(tetrahydrofuran)vanadium
• CAS No.: 78614-84-3
• Molecular Formula: C₂₂H₈F₁₅OV
• Molecular Weight: 624.222
• Mol file: 78614-84-3.mol

Synonyms:tris(pentafluorophenyl)(tetrahydrofuran)vanadium

Chemical Property of tris(pentafluorophenyl)(tetrahydrofuran)vanadium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tris(pentafluorophenyl)(tetrahydrofuran)vanadium

There total 1 articles about tris(pentafluorophenyl)(tetrahydrofuran)vanadium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

Vanadium (III) chloride-(tris-tetrahydrofuran) (131063-11-1,16997-51-6,19559-06-9) + pentafluorophenyl lithium (1076-44-4) → tris(pentafluorophenyl)(tetrahydrofuran)vanadium (78614-84-3)

Guidance literature:

In tetrahydrofuran; byproducts: LiCl; 1 mol of complex was slowly added to an THF soln. of 3 mol RLi at -78°C, the temp. was slowly raised to room temp. with stirring (Ar atm.);; filtered, evapd., ppt. was dissoved in Et2O, filtered, evapd., washed with pentane, cooled; elem. anal.;;

DOI:10.1016/S0022-328X(00)82672-8

Reference yield: 94.0%

tris(pentafluorophenyl)(tetrahydrofuran)vanadium (78614-84-3) → (C6F5)V(OCOC6F5)2*C4H8O

Guidance literature:

With carbon dioxide; In tetrahydrofuran; A soln. of complex in THF and CO2 were plaxed in an evacuated ampoule, 2 h at 20°C; evapd. under vac., ppt. was dried in vac.; elem. anal.;;

DOI:10.1016/S0022-328X(00)82672-8

Reference yield:

tris(pentafluorophenyl)(tetrahydrofuran)vanadium (78614-84-3) + mercury dichloride → mercury(I) chloride (104923-33-3) + vanadiumtetrachloride (7632-51-1) + pentafluorophenylmercury chloride (941-78-6)

Guidance literature:

In tetrahydrofuran; HgCl2 was added to a soln. of complex in THF (Ar atm.);; filtered, evapd. under vac., ppt. was solved in hot water, cooled;;

DOI:10.1016/S0022-328X(00)82672-8

upstream raw materials:

Vanadium (III) chloride-(tris-tetrahydrofuran)

pentafluorophenyl lithium

Downstream raw materials:

mercury(I) chloride

vanadiumtetrachloride

pentafluorophenylmercury chloride

C₁₈ClF₁₅V

Refernces