Ruthenium, dicarbonyldichlorobis(triphenylphosphine)-

Base Information

• Chemical Name: Ruthenium, dicarbonyldichlorobis(triphenylphosphine)-
• CAS No.: 14564-35-3
• Molecular Formula: C₃₈H₃₀Cl₂O₂P₂Ru
• Molecular Weight: 752.579
• Hs Code.: 28439090
• European Community (EC) Number: 238-605-9
• Mol file: 14564-35-3.mol

Synonyms:14564-35-3;Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II);Ruthenium, dicarbonyldichlorobis(triphenylphosphine)-;Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride;DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II);carbon monoxide;dichlororuthenium;triphenylphosphane;C38H30Cl2O2P2Ru;C38-H30-Cl2-O2-P2-Ru;MFCD00009594;RuCl2(CO)2(PPh3)2;AKOS025310741;AC-5528;SC10303;DICHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II);BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) DICARBONYL CHLORIDE;DICARBONYLDICHLOROBIS(TRIPHENYLPHOSPHINE)RUTHENIUM;DICARBONYLDICHLOROBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II);DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II);RUTHENIUM(II)BIS(TRIPHENYLPHOSPHINE)DICHLOROCARBONYL

Chemical Property of Ruthenium, dicarbonyldichlorobis(triphenylphosphine)-

Chemical Property:

• Appearance/Colour: white powder
• Vapor Pressure: 4.74E-05mmHg at 25°C
• Melting Point: 230-235oC
• Boiling Point: 360 °C at 760 mmHg
• Flash Point: 181.7 °C
• PSA: 27.18000
• LogP: 7.85260
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 752.014150
• Heavy Atom Count: 45
• Complexity: 214

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), min. 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ru]Cl

Technology Process of Ruthenium, dicarbonyldichlorobis(triphenylphosphine)-

There total 63 articles about Ruthenium, dicarbonyldichlorobis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tricarbonylbis(triphenylphosphine)ruthenium(0) (20332-49-4,14741-36-7) + nitrosylchloride (2696-92-6) → dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) (32240-63-4,29079-66-1,15709-57-6,36500-84-2,15709-73-6,14564-35-3) + trichloronitrosylbis(triphenylphosphine)ruthenium

Guidance literature:

In methanol; dichloromethane; addn. of NOCl soln. to Ru complex soln.; addn. of hot methanol; vigorously stirring; pptn.; centrifuging; washing (methanol, ether); drying (vac.); keeping centrifugate, 3-4h; pptn.; centrifuging; washing (methanol, ether); drying (vac.); elem. anal.;

Reference yield: 74.0%

{Ru(CO)2(NS2)(P(C6H5)3)2}(1+)*(SbCl6)(1-)={Ru(CO)2(NS2)(P(C6H5)3)2}(SbCl6) → dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) (32240-63-4,29079-66-1,15709-57-6,36500-84-2,15709-73-6,14564-35-3)

Guidance literature:

In dichloromethane; 2 h stirring, filtration, diln. in hot methanol, product filtered off, washed with methanol and diethyl ether, dried under vacuum; elem. anal.;

DOI:10.1016/S0020-1693(00)82208-2

Reference yield: 45.0%

trans-dichloro(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-O,O')bis(triphenylphosphine)ruthenium(II) → dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) (32240-63-4,29079-66-1,15709-57-6,36500-84-2,15709-73-6,14564-35-3) + chloro(carbonyl)(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)bis(triphenylphosphine)ruthenium(III)

Guidance literature:

With CO; In benzene; refuxing soln. of Ru-complex in benzene(CO atmosphere, 6 h); cooling, evapn. to dryness (reduced pressure), recrystn. (CH2Cl2-EtOH), washing (EtOH, light petroleum), drying (vac.); elem. anal.;

DOI:10.1016/S0277-5387(00)80353-8

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

trithiazyl trichloride

Ru(CO)3(PPh₃)3

RuCl₂(P(C₆H₅)3)(C₅H₃N(CH₂CHCH₂)2)

Downstream raw materials:

cis-dicarbonyldichlorobis(triphenylphosphine)ruthenium(II)

all-trans-[RuCl₂(CO)2(PPh₃)2]

{(triphenylphosphine)(carbonyl)2ruthenium(μ2-ethanethiolato)(μ3-ethanethiolato)sodium(THF)}2

cis,cis,trans-Cl((Et)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Refernces

• 1、 Vasapollo, Giuseppe,Nobile, Cosimo Francesco,Latronico, Mario,Lanfranchi, Maurizio,Pellinghelli, Maria Angela. "Olefin ligands II. Syntheses of 2,6-diallylpyridine (DAP) complexes of iridium(I), ruthenium(II), palladium(II) and platinum(II); crystal structures of and ". . p. 429 - 440. Retrieved 1987.
• 2、 Colson, Stephen F.,Robinson, Stephen D.. "". . p. 2179 - 2182. Retrieved 1989.
• 3、 Pandey, Krishna K.. "". . p. 9 - 10. Retrieved 1986.
• 4、 Piacenti,Bianchi,Benedetti,Braca. "On the reactivity of tris(triphenylphosphine)triruthenium enneacarbonyl". . p. 1815 - 1817. Retrieved 1968.
• 5、 Hill, Anthony F.,Rae, A. David,Schultz, Madeleine,Willis, Anthony C.. "Bis(alkynyl), metallacyclopentadiene, and diphenylbutadiyne complexes of ruthenium". . p. 1325 - 1338. Retrieved 2008/10/09.