trithiazyl chloride

Base Information

• Chemical Name: trithiazyl chloride
• CAS No.: 105454-00-0
• Molecular Formula: Cl₃N₃S₃
• Molecular Weight: 244.577
• Mol file: 105454-00-0.mol

Synonyms:

Chemical Property of trithiazyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trithiazyl chloride

There total 2 articles about trithiazyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

thiodiazyl dichloride + chlorine (7782-50-5) → trithiazyl trichloride (105454-00-0,105453-99-4,5964-00-1) + sulfur dichloride (10545-99-0)

Guidance literature:

Reference yield:

thoidithiazyl dichloride → trithiazyl trichloride (105454-00-0,105453-99-4,5964-00-1) + sulfur dichloride (10545-99-0)

Guidance literature:

With chlorine; In neat (no solvent); at ambient temp.;;

Reference yield: 90.0%

trithiazyl trichloride (105454-00-0,105453-99-4,5964-00-1) + (PPh3Me)2{(MoCl3(NO)2)2} → (PPh3Me)2{(MoCl4(NO))2(μ-S2N2)}

Guidance literature:

In dichloromethane; exclusion of moisture; a soln. of (NSCl3)3 is dropped into a suspension of the Mo-complex, both in CH2Cl2, with stirring for 15 min; after standing for 24 h at room temp. and then for several days at 4°C the product crystallizes;; filtration; washing (CH2Cl2); drying (N2); sepn. from a black solid (the formation of this impurity can be avoided by use of sufficient (NSCl3)3); elem. anal.;;

upstream raw materials:

chlorine

Downstream raw materials:

dicarbonyldichlorobis(triphenylphosphine)ruthenium(II)

tetrasulfur tetranitride

meso-tetraphenylporphyrin iron(III) chloride

thiotrithiazyl chloride

Refernces