Iodine radical

Base Information

• Chemical Name: Iodine radical
• CAS No.: 14362-44-8
• Molecular Formula: I
• Molecular Weight: 126.904
• Mol file: 14362-44-8.mol

Synonyms:14362-44-8;Iodine Atom;iodine radical;iodine(.);monoiodine;CHEBI:33115;AKOS024438077;I(.)

Chemical Property of Iodine radical

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.88570
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 126.90447
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [I]

Technology Process of Iodine radical

There total 239 articles about Iodine radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

carbon tetraiodide (507-25-5) → carbonic-acid (463-79-6) + iodide (14362-44-8,20461-54-5,69239-56-1)

Guidance literature:

With potassium hydroxide; water; In methanol; water;

DOI:10.1021/jo01224a009

Reference yield:

hydroxylamine (7803-49-8) + iodine (7553-56-2,12190-71-5,8031-47-8) → iodide (14362-44-8,20461-54-5,69239-56-1) + dinitrogen monoxide (10024-97-2)

Guidance literature:

In water; byproducts: H(1+), H2O; excess of hydroxylamine, in presence of excess I(1-), 25°C, I=0.50 M NaClO4; varying acidity (1.15-9.90 mM HClO4 or acetate or phosphatebuffer or unbuffered soln.; pH=3.44-6.84); not isolated, reaction followed by UV/VIS spectroscopy; Kinetics;

DOI:10.1021/ic00128a021

Reference yield:

hydroxylammonium + iodate (15454-31-6) → iodide (14362-44-8,20461-54-5,69239-56-1) + hydrogen cation + dinitrogen monoxide (10024-97-2)

Guidance literature:

In further solvent(s); in HCl soln.;

upstream raw materials:

4-cyanophenolate

Thiocyanate

iodate

iodine

Downstream raw materials:

methyl iodide

chloride

iodine

triiodide^(1-)

Refernces

• 1、 Griffith, R. O.,Jobin, R. S.,McKeown, A.. "". . p. 316 - 325. Retrieved 1938.
• 2、 Griffith, R. O.,Irving, R.. "". . p. 305 - 312. Retrieved 1949.
• 3、 Schoch, E. P.. "". . p. 1422 - 1422. Retrieved 1904.
• 4、 Ershov,Janata. "The reduction of I2 by 1-hydroxyalkyl radicals in aqueous solution. A pulse radiolysis study". . p. 195 - 198. Retrieved 2003.
• 5、 Hogness, T. R.,Harkness, R. W.. "". . p. 784 - 784. Retrieved 1928.
• 6、 Adegite, A.,Egboh, H.. "". . p. 1 - 4. Retrieved 1977.
• 7、 Xu, Li,Csek?, Gy?rgy,Kégl, Tamás,Horváth, Attila K.. "General pathway of sulfur-chain breakage of polythionates by iodine confirmed by the kinetics and mechanism of the pentathionate-iodine reaction". . p. 7837 - 7843. Retrieved 2012.
• 8、 Kalamarides, A.,Walter, C.W.,Lindsay, B.G.,Smith, K.A.,Dunning, F.B.. "". . p. 4411 - 4413. Retrieved 1989.
• 9、 Thomas, T. R.,Pence, D. T.,Hasty, R. A.. "". . p. 183 - 186. Retrieved 1980.
• 10、 Skrabal, A.. "". . . Retrieved 1911.