{SF₃}⁽¹⁺⁾*{AsF₆}^(1-)=SF₃AsF₆

Base Information

• Chemical Name: {SF₃}⁽¹⁺⁾*{AsF₆}^(1-)=SF₃AsF₆
• CAS No.: 30313-36-1
• Molecular Formula: AsF₆*F₃S
• Molecular Weight: 277.973
• Mol file: 30313-36-1.mol

Synonyms:{SF₃}⁽¹⁺⁾*{AsF₆}^(1-)=SF₃AsF₆

Chemical Property of {SF₃}⁽¹⁺⁾*{AsF₆}^(1-)=SF₃AsF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {SF₃}⁽¹⁺⁾*{AsF₆}^(1-)=SF₃AsF₆

There total 3 articles about {SF₃}⁽¹⁺⁾*{AsF₆}^(1-)=SF₃AsF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichlorodithionitronium hexafluoroarsenate (60563-08-8) + chlorine monofluoride (7790-89-8) → pentafluorosulfanyl chloride (13780-57-9) + {SF3}(1+)*{AsF6}(1-)=SF3AsF6 (30313-36-1) + difluoro-dithionitronium hexafluoroarsenate(V) + sulfur tetrafluoride (7783-60-0) + thionyl fluoride (7783-42-8)

Guidance literature:

With fluorosulfonylchloride; In not given; SO2ClF and ClF were condensed onto (SCl)2NAsF6, mixt. was warmed to room temp. with srirring, 5 h; volatiles were removed, products were not isolated; products were analized by IR;

DOI:10.1039/DT9830001961

Reference yield:

dithionitronium hexafluoroarsenate (80485-40-1) + fluorine (7782-41-4) → {SF3}(1+)*{AsF6}(1-)=SF3AsF6 (30313-36-1) + bis(difluorothio)nitronium hexafluoroarsenate(V) (88446-29-1) + difluoro-dithionitronium hexafluoroarsenate(V) + sulfur(VI) hexafluoride (2551-62-4)

Guidance literature:

With fluorosulfonyl fluoride; In not given; SO2F2 and F2 were added to S2NAsF6 at -196°C, mixt. was stirred for 4 h while held at -78°C, mixt. was stirred at room temp. for 20h; volatiles were removed, products were not isolated; products were analized by IR;

DOI:10.1039/DT9830001961

Reference yield:

thiazyl trifluoride (15930-75-3) + xenon difluoride * AsF5 (26024-71-5) → {SF3}(1+)*{AsF6}(1-)=SF3AsF6 (30313-36-1) + cis-difluorodiazene (13812-43-6)

Guidance literature:

In further solvent(s); byproducts: Xe; (inert atm.); condensation of NSF3 onto xenon compd. at -196°C, warming to -78°C and then to -20°C for 6 h, warming to 0°C for 21 h; evapn. at -50°C for 5 min and then at -45°C for 15 min, Raman and NMR;

DOI:10.1021/ic900651n

upstream raw materials:

dithionitronium hexafluoroarsenate

fluorine

dichlorodithionitronium hexafluoroarsenate

chlorine monofluoride

Refernces

• 1、 Smith, Gregory L.,Schrobilgen, Gary J.. "On the reactivity of F3S≡NXeF+: Syntheses and structural characterizations of [F4S=N-Xe - N≡SF 3][AsF6], a rare example of a N-Xe-N Linkage, and [F 3S(N≡SF3)2][AsF6]". . p. 7714 - 7728. Retrieved 2011/02/27.